Surface Modification by Electrostatic Self-Assembly Followed by Covalent Fixation

Sticks and bonds: Surface‐modifying agents can be functionalized with ionic groups that enable high exhaustion from a processing bath through electrostatic self‐assembly. Using cyclic oniums as the ionic functional groups, thermally induced ring‐opening converts the ionic bonds to covalent bonds, th...

Full description

Saved in:
Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 51; no. 8; pp. 1849 - 1852
Main Authors Foston, Marcus, Hubbell, Christopher, Park, Doh-Yeon, Cook, Fred, Tezuka, Yasuyuki, Beckham, Haskell W.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 20.02.2012
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
Covalence
Covalent bonds
Electrostatics
Exhaustion
Fixation
Functional groups
reactive ions
ring-opening
Self assembly
surface modification
Online AccessGet full text

Cover

More Information
Summary:Sticks and bonds: Surface‐modifying agents can be functionalized with ionic groups that enable high exhaustion from a processing bath through electrostatic self‐assembly. Using cyclic oniums as the ionic functional groups, thermally induced ring‐opening converts the ionic bonds to covalent bonds, thus lending permanency to the modification of the surface.
Bibliography:US Department of Commerce
Portions of this work were funded by the National Textile Center through the US Department of Commerce. We are grateful to Prof. Mohan Srinivasarao for carefully reading the manuscript.
ark:/67375/WNG-65PX4D84-C
istex:7A749307CE3DA604F0E3A992EE9753C89A44AF21
ArticleID:ANIE201106968
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201106968