真空热解松木粉制备生物油
为研究与开拓高品位生物油的制备方法,该文以松木粉为原料,采用真空热解的方法制备生物油.讨论了150-830μm 的4种不同粒径大小、400-600℃的5种不同反应温度对真空热解的影响,对其原因进行讨论与分析;并对最优条件下的真空热解气液相产物进行表征.试验结果表明,在500℃反应温度下,250-380μm 粒径松木粉真空热解得到生物油产率最高,可达52.06%;真空热解生物油的黏度较低,流动性能好,高附加值化合物较多,这些特性使真空热解生物油作为提取化学品的原料成为可能,该研究为生物质制备高品位生物油提供参考....
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| Published in | 农业工程学报 Vol. 29; no. 1; pp. 196 - 201 |
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| Main Author | |
| Format | Journal Article |
| Language | Chinese |
| Published |
中国科学院可再生能源与天然气水合物重点实验室,广州 510640%中国科学院广州能源研究所,广州 510640%天津大学环境科学与工程学院,天津 300072
2013
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1002-6819 |
| DOI | 10.3969/j.issn.1002-6819.2013.01.026 |
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| Summary: | 为研究与开拓高品位生物油的制备方法,该文以松木粉为原料,采用真空热解的方法制备生物油.讨论了150-830μm 的4种不同粒径大小、400-600℃的5种不同反应温度对真空热解的影响,对其原因进行讨论与分析;并对最优条件下的真空热解气液相产物进行表征.试验结果表明,在500℃反应温度下,250-380μm 粒径松木粉真空热解得到生物油产率最高,可达52.06%;真空热解生物油的黏度较低,流动性能好,高附加值化合物较多,这些特性使真空热解生物油作为提取化学品的原料成为可能,该研究为生物质制备高品位生物油提供参考. |
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| Bibliography: | 11-2047/S agriculture, biomass, pyrolysis, yields, bio-oil Xu Ying, Wang Tiejun, Ma Longlong, Zhang Qi, Chen Guany （1. Key Laboratory of Renewable Energy and Gas Hydrate, Chinese Academy of Sciences, Guangzhou 510640, China; 2. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China; 3. School of Environmental Science and Technology, Tianjin University, Tianjin 300072, China） Bio-oil, biomass fast pyrolysis product, has lots of inferior quality. These drawbacks result in a serious impediment for bio-oil’s practical applications. Although there are many methods for upgrading bio-oil, there is no effective way to solve the problems existing in bio-oil. The aim of the paper is to find a breakthrough from the bio-oil preparation, which using vacuum pyrolysis method to obtain bio-oil from pine straw at bench scale. The influence of temperatures （400-600℃） and biomass dimensions （150-830 μm） on vacuum pyrolysis were investigated. The reaction temperatures were set at 400, 450, 50 |
| ISSN: | 1002-6819 |
| DOI: | 10.3969/j.issn.1002-6819.2013.01.026 |