Crystal structure, thermal expansion and electrical conductivity of LaCo x Ni y Mo z O 3
The effect of Mo-substitution was investigated for the LaCo Ni Mo O system, obtaining single-phase perovskite for Mo-substitutions up to 20 at%. The crystal structure of the perovskite changed from rhombohedral, orthorhombic to monoclinic with increasing Mo-content. The thermal expansion was suppres...
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| Published in | Dalton transactions : an international journal of inorganic chemistry Vol. 45; no. 39; pp. 15290 - 15293 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
England
04.10.2016
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| Online Access | Get full text |
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| Summary: | The effect of Mo-substitution was investigated for the LaCo
Ni
Mo
O
system, obtaining single-phase perovskite for Mo-substitutions up to 20 at%. The crystal structure of the perovskite changed from rhombohedral, orthorhombic to monoclinic with increasing Mo-content. The thermal expansion was suppressed by Mo-substitution, while the electrical conductivity was also suppressed, but remained relatively high. |
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| ISSN: | 1477-9226 1477-9234 |
| DOI: | 10.1039/C6DT03265F |