CHIRALITY CONTROLLED BIOMIMETIC OLEFIN CYCLIZATION

Chiral oxygen functionality located in a polyene chain controls the chirality during mercury (II) triflate induced biomimetic olefin cyclization to give carbocycles under a virtually complete chirality transfer.

Saved in:
Bibliographic Details
Published inChemical & pharmaceutical bulletin Vol. 41; no. 4; pp. 791 - 792
Main Authors NISHIZAWA, Mugio, TAKENAKA, Hideyuki, KOHNO, Tetsuyuki, TAKAO, Hiroko, YAMADA, Hidetoshi
Format Journal Article
LanguageEnglish
Published TOKYO The Pharmaceutical Society of Japan 1993
Pharmaceutical Soc Japan
Maruzen
Japan Science and Technology Agency
Subjects
biomimetic
carbamate
Chemistry
Chemistry, Medicinal
Chemistry, Multidisciplinary
chirality control
diastereoselective
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Life Sciences & Biomedicine
mercury triflate
olefin cyclization
Organic chemistry
Pharmacology & Pharmacy
Physical Sciences
Preparations and properties
Science & Technology
DIASTEREOSELECTIVE
MERCURY TRIFLATE
CARBAMATE
OLEFIN CYCLIZATION
INDUCTION
BIOMIMETIC
CHIRALITY CONTROL
Substituent effect
Intramolecular reaction
Cyclization
Vinylic compound
Biomimetic reaction
Bicyclic compound
Chiral compound
Oxygen heterocycle
Organic carbamate
Ethylenic compound
Diastereoselectivity
Online AccessGet full text

Cover

More Information
Summary:Chiral oxygen functionality located in a polyene chain controls the chirality during mercury (II) triflate induced biomimetic olefin cyclization to give carbocycles under a virtually complete chirality transfer.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.41.791