Precipitation Sequence in the Mg-Gd-Y System Investigated by HRTEM and HAADF-STEM

• Published in: Keikinzoku Vol. 64; no. 7; p. 292
• Main Authors: Matsuoka, Yuuki, Matsuda, Kenji, Watanabe, Katsumi, Nakamura, Junya, Lefebvre, Williams, Nakagawa, Daisuke, Saikawa, Seiji, Ikeno, Susumu
• Format: Journal Article
• Language: English
• Published: 01.07.2014
• Subjects: Electron microscopy; Hexagons; Magnesium base alloys; Networks; Nucleation; Precipitates; Precipitation; Quenching
• ISSN: 0451-5994; 1880-8018
• DOI: 10.2320/matertrans.L-M2014824

In this work, the early stage of precipitation have been investigated in a Mg-2.9 at% Gd-0.8 at% Y by high angle annular dark field-scanning transmission electron microscopy (HAADF-STEM) and high resolution transmission electron microscopy (HRTEM). At the underaged condition, precipitates observed by HRTEM were classified as follows; mono-layer, a part of beta ", beta '. By HAADF-STEM, zig-zag structure, small hexagonal network, and beta ' could be recognized. The small "super hexagons" are the first precipitates in this alloy. This structure, referred to as the pre beta "-phase, displays a short range similar to the one present in the D0 sub(19) structure. This phase is formed during quenching and prevails over the zig-zag structure at the beginning of aging. The zig-zag contrast is one of the variations of this small hexagonal network or heterogeneous nucleation during aging. Finally, we concluded that the proposed precipitation sequence is as follows: SSSS arrow right pre beta "-phase having D0 sub(19)-SRO arrow right beta "-phase arrow right beta '-phase. The comparison of HRTEM, HAADF-STEM and simulated images have helped to clarify the meaning of HRTEM features.