Unraveling Non‐Uniform Strain‐Induced Crystallization Near a Crack Tip in Natural Rubber

• Published in: Advanced science Vol. 11; no. 12; pp. e2307741 - n/a
• Main Authors: Mai, Thanh‐Tam, Yasui, Tomohiro, Tanaka, Ruito, Masunaga, Hiroyasu, Kabe, Taizo, Tsunoda, Katsuhiko, Sakurai, Shinichi, Urayama, Kenji
• Format: Journal Article
• Language: English
• Published: Germany John Wiley & Sons, Inc 01.03.2024; John Wiley and Sons Inc; Wiley
• Subjects: Crystallization; Diffraction; elastomer; natural rubber; Rubber; rubber elasticity; synchrotron radiation; crystallization; natural rubber; rubber elasticity; elastomer; synchrotron radiation
• ISSN: 2198-3844; 2198-3844
• DOI: 10.1002/advs.202307741

Strain‐induced crystallization (SIC) in natural rubber (NR) near crack tips significantly enhances crack growth resistance, but understanding the interplay between local strain field and crystallization remains challenging due to confined and heterogeneous characteristics. Using micro‐scale digital image correlation (DIC) and scanning wide‐angle X‐ray diffraction (WAXD, with a narrow 10 µm square beam), this study maps local strain tensor properties and SIC in the vicinity of the crack tip and its peripheral zone (≈3 mm × 1 mm area). The analysis reveals a significant correlation between these properties. In the peripheral zone, there is a noticeable deviation of both the principal strain axis and the crystal orientation from the crack opening direction. These deviations are linearly correlated, which indicates that shear strain plays a significant role in determining the crystal orientation. Crucially, the maximum tensile component in the tensor of local principal strains predominantly dictates local crystallinity. This simplicity is attributed to the limited variation in types of deformation within the SIC region, with corresponding to deformations falling between planar and uniaxial stretching. These findings pave the way for predicting crystallinity distribution using solely strain field data, offering valuable insights into the role of SIC in enhancing the crack growth resistance of NR. This study explores the interplay between non‐uniform strain and crystallization near crack‐tips in natural rubber, employing micro‐scale DIC and micro‐beam scanning X‐ray scattering. Local maximum tensile strain predominantly dictates local crystallinity, while shear strain governs crystal orientation. These findings shed light on how crystallization contributes to the crack growth resistance of natural rubber.