Studies on the adsorption of chromium(VI) onto 3-Mercaptopropionic acid coated superparamagnetic iron oxide nanoparticles

• Published in: Journal of colloid and interface science Vol. 425; no. 425; pp. 36 - 43
• Main Authors: Burks, T., Avila, M., Akhtar, F., Göthelid, M., Lansåker, P.C., Toprak, M.S., Muhammed, M., Uheida, A.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier Inc 01.07.2014; Elsevier
• Subjects: 3-Mercaptopropionic acid; Adsorbents; Adsorption; Chemisorption; Chemistry; Chromium; Colloidal state and disperse state; Engineering Science with specialization in Solid State Physics; Exact sciences and technology; General and physical chemistry; Iron oxides; Nanoparticles; Physical and chemical studies. Granulometry. Electrokinetic phenomena; SPION; Sulfonates; Surface physical chemistry; Teknisk fysik med inriktning mot fasta tillståndets fysik; X-ray photoelectron spectroscopy; Chromium; 3-Mercaptopropionic acid; Adsorption; SPION; Iron oxide; Acids; Nanoparticle; Transition element compounds; Superparamagnetism; Chromium VI
• ISSN: 0021-9797; 1095-7103; 1095-7103
• DOI: 10.1016/j.jcis.2014.03.025

[Display omitted] •Developed an effective adsorbent by combining SPION and 3-Mercaptopropionic acid.•3-MPA coated SPION showed higher loading capacity of Cr(VI) than common adsorbents.•Mechanism of interaction was proposed based on FTIR and XPS analyses. Chromium (Cr) in the form of Cr(VI) is deemed toxic in water due to its mutagenic and carcinogenic properties. For the successful removal of Cr(VI), we demonstrate a novel adsorbent consisting of superparamagnetic iron oxide nanoparticles (SPION) functionalized with 3-Mercaptopropionic acid (3-MPA). Fourier transform infrared spectroscopy (FT-IR) confirmed the functionalization of nanoparticles and presence of sulfonate groups. Batch adsorption experiments showed that the functionalized adsorbent recovered 45mg of Cr(VI)/g of 3-MPA coated SPION at initial concentration of 50mg/L aqueous solution at pH 1 with less than 1% of Fe dissolution from SPION. The results from X-ray photoelectron spectroscopy confirmed that Cr(VI) chemisorbed onto the adsorbent. Hence, the XPS spectra did not indicate any reduction of Cr(VI) to Cr(III) upon adsorption. The adsorption data were better fitted for the Freundlich model. Moreover, the Cr(VI) adsorption kinetics on functionalized SPION followed a pseudo-second order rate, revealing chemisorption as the dominant mechanism. The high Cr(VI) removal, rapid adsorption kinetics and stability of adsorbent indicate that 3-MPA coated SPION could be an efficient adsorbent for the removal of Cr(VI).