Synthetic studies on palau’amine. Construction of the cyclopentane core via an asymmetric 1,3-dipolar cycloaddition

The cyclopentane core of palau’amine has been constructed in optically pure form through the use of an asymmetric azomethine ylid [1,3]-dipolar cycloaddition reaction.

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Bibliographic Details
Published inTetrahedron letters Vol. 51; no. 50; pp. 6557 - 6559
Main Authors Namba, Kosuke, Inai, Makoto, Sundermeier, Uta, Greshock, Thomas J., Williams, Robert M.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 15.12.2010
Elsevier
Subjects
Amino acid
Asymmetry
Chemistry
Chemistry, Organic
Construction
Cycloaddition
Dipolar cycloaddition
Physical Sciences
Science & Technology
Spiro-guanidine
Tetrahedrons
Amino acid
Spiro-guanidine
Dipolar cycloaddition
CONCISE
DIELS-ALDER REACTIONS
ENANTIOSELECTIVE SYNTHESIS
STRATEGY
AZOMETHINE YLIDE
RELATIVE CONFIGURATION
OROIDIN
STEREOCONTROLLED SYNTHESIS
ACCESS
ALKALOIDS
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Summary:The cyclopentane core of palau’amine has been constructed in optically pure form through the use of an asymmetric azomethine ylid [1,3]-dipolar cycloaddition reaction.
Bibliography:NIH RePORTER
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2010.10.037