Carrier multiplication in van der Waals layered transition metal dichalcogenides

• Published in: Nature communications Vol. 10; no. 1; p. 5488
• Main Authors: Kim, Ji-Hee, Bergren, Matthew R, Park, Jin Cheol, Adhikari, Subash, Lorke, Michael, Frauenheim, Thomas, Choe, Duk-Hyun, Kim, Beom, Choi, Hyunyong, Gregorkiewicz, Tom, Lee, Young Hee
• Format: Journal Article
• Language: English
• Published: England Nature Publishing Group 02.12.2019; Nature Publishing Group UK; Nature Portfolio
• Subjects: Bleaches; Carbon nanotubes; Chalcogenides; Energy conservation; Energy conversion; Energy conversion efficiency; Energy dissipation; Holes (electron deficiencies); Materials selection; Multiplication; Nanomaterials; Nanotechnology; Nanotubes; Photovoltaic cells; Photovoltaics; Quantum dots; Solar cells; Spectroscopy; Transition metal compounds
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/s41467-019-13325-9

Carrier multiplication (CM) is a process in which high-energy free carriers relax by generation of additional electron-hole pairs rather than by heat dissipation. CM is promising disruptive improvements in photovoltaic energy conversion and light detection technologies. Current state-of-the-art nanomaterials including quantum dots and carbon nanotubes have demonstrated CM, but are not satisfactory owing to high-energy-loss and inherent difficulties with carrier extraction. Here, we report CM in van der Waals (vdW) MoTe and WSe films, and find characteristics, commencing close to the energy conservation limit and reaching up to 99% CM conversion efficiency with the standard model. This is demonstrated by ultrafast optical spectroscopy with independent approaches, photo-induced absorption, photo-induced bleach, and carrier population dynamics. Combined with a high lateral conductivity and an optimal bandgap below 1 eV, these superior CM characteristics identify vdW materials as an attractive candidate material for highly efficient and mechanically flexible solar cells in the future.