Dual-plasmonic Au@Cu7S4 yolk@shell nanocrystals for photocatalytic hydrogen production across visible to near infrared spectral region

• Published in: Nature communications Vol. 15; no. 1; p. 413
• Main Authors: Tsao, Chun-Wen, Narra, Sudhakar, Kao, Jui-Cheng, Lin, Yu-Chang, Chen, Chun-Yi, Chin, Yu-Cheng, Huang, Ze-Jiung, Huang, Wei-Hong, Huang, Chih-Chia, Luo, Chih-Wei, Chou, Jyh-Pin, Ogata, Shigenobu, Sone, Masato, Huang, Michael H., Chang, Tso-Fu Mark, Lo, Yu-Chieh, Lin, Yan-Gu, Diau, Eric Wei-Guang, Hsu, Yung-Jung
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 09.01.2024; Nature Publishing Group; Nature Portfolio
• Subjects: 140/125; 639/301/299/890; 639/638/77/890; Bolts; Catalysts; Crystals; Gold; Humanities and Social Sciences; Hydrogen; Hydrogen production; Maneuvers; multidisciplinary; Nanocrystals; Near infrared radiation; Nuts (fasteners); Photocatalysis; Plasmonics; Quantum dots; Science; Science (multidisciplinary); Solar energy; Star maps; Surface plasmon resonance; Yolk
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/s41467-023-44664-3

Near infrared energy remains untapped toward the maneuvering of entire solar spectrum harvesting for fulfilling the nuts and bolts of solar hydrogen production. We report the use of Au@Cu 7 S 4 yolk@shell nanocrystals as dual-plasmonic photocatalysts to achieve remarkable hydrogen production under visible and near infrared illumination. Ultrafast spectroscopic data reveal the prevalence of long-lived charge separation states for Au@Cu 7 S 4 under both visible and near infrared excitation. Combined with the advantageous features of yolk@shell nanostructures, Au@Cu 7 S 4 achieves a peak quantum yield of 9.4% at 500 nm and a record-breaking quantum yield of 7.3% at 2200 nm for hydrogen production in the absence of additional co-catalysts. The design of a sustainable visible- and near infrared-responsive photocatalytic system is expected to inspire further widespread applications in solar fuel generation. In this work, the feasibility of exploiting the localized surface plasmon resonance property of self-doped, nonstoichiometric semiconductor nanocrystals for the realization of wide-spectrum-driven photocatalysis is highlighted. Near infrared energy remains untapped toward the maneuvering of entire solar spectrum harvesting for fulfilling nuts and bolts of solar hydrogen production. Here, the authors report the use of Au@Cu 7 S 4 yolk@shell nanocrystals for hydrogen production from untapped near infrared energy.