Linear polystyrene-stabilized PdO nanoparticle-catalyzed Mizoroki-Heck reactions in water

Linear polystyrene-stabilized PdO nanoparticles (PS-PdONPs) were prepared by thermal decomposition of Pd(OAc)(2) in the presence of polystyrene. X-ray diffraction (XRD) and transmission electron microscopy (TEM) indicated the production of PdO nanoparticles. The loading of palladium was determined b...

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Published inMolecules (Basel, Switzerland) Vol. 16; no. 11; pp. 9067 - 9076
Main Authors Ohtaka, Atsushi, Yamaguchi, Tomohiro, Teratani, Takuto, Shimomura, Osamu, Nomura, Ryôki
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 27.10.2011
MDPI
Subjects
Acids
Catalysis
Metal Nanoparticles - chemistry
Microscopy, Electron, Transmission
Mizoroki-Heck reaction
Molecular Structure
Nanoparticles
Palladium
Palladium - chemistry
PdO nanoparticles
polystyrene
Polystyrenes - chemistry
Potassium
Spectrum Analysis - methods
water
Water - chemistry
X-Ray Diffraction
Japan
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Abstract Linear polystyrene-stabilized PdO nanoparticles (PS-PdONPs) were prepared by thermal decomposition of Pd(OAc)(2) in the presence of polystyrene. X-ray diffraction (XRD) and transmission electron microscopy (TEM) indicated the production of PdO nanoparticles. The loading of palladium was determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). PS-PdONPs exhibited high catalytic activity for Mizoroki-Heck reactions under air in water and could be recycled without loss of activity.
AbstractList Linear polystyrene-stabilized PdO nanoparticles (PS-PdONPs) were prepared by thermal decomposition of Pd(OAc)2 in the presence of polystyrene. X-ray diffraction (XRD) and transmission electron microscopy (TEM) indicated the production of PdO nanoparticles. The loading of palladium was determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). PS-PdONPs exhibited high catalytic activity for Mizoroki-Heck reactions under air in water and could be recycled without loss of activity.
Linear polystyrene-stabilized PdO nanoparticles (PS-PdONPs) were prepared by thermal decomposition of Pd(OAc) 2 in the presence of polystyrene. X-ray diffraction (XRD) and transmission electron microscopy (TEM) indicated the production of PdO nanoparticles. The loading of palladium was determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). PS-PdONPs exhibited high catalytic activity for Mizoroki-Heck reactions under air in water and could be recycled without loss of activity.
Author Shimomura, Osamu
Ohtaka, Atsushi
Yamaguchi, Tomohiro
Nomura, Ryôki
Teratani, Takuto
AuthorAffiliation 1 Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi, Osaka 535-8585, Japan
2 Nanomaterials and Microdevices Research Center, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi, Osaka 535-8585, Japan
AuthorAffiliation_xml – name: 1 Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi, Osaka 535-8585, Japan
– name: 2 Nanomaterials and Microdevices Research Center, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi, Osaka 535-8585, Japan
Author_xml – sequence: 1
  givenname: Atsushi
  surname: Ohtaka
  fullname: Ohtaka, Atsushi
  email: otaka@chem.oit.ac.jp
  organization: Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi, Osaka, Japan. otaka@chem.oit.ac.jp
– sequence: 2
  givenname: Tomohiro
  surname: Yamaguchi
  fullname: Yamaguchi, Tomohiro
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  surname: Shimomura
  fullname: Shimomura, Osamu
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  givenname: Ryôki
  surname: Nomura
  fullname: Nomura, Ryôki
BackLink https://www.ncbi.nlm.nih.gov/pubmed/22033141$$D View this record in MEDLINE/PubMed
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Snippet Linear polystyrene-stabilized PdO nanoparticles (PS-PdONPs) were prepared by thermal decomposition of Pd(OAc)(2) in the presence of polystyrene. X-ray...
Linear polystyrene-stabilized PdO nanoparticles (PS-PdONPs) were prepared by thermal decomposition of Pd(OAc)2 in the presence of polystyrene. X-ray...
Linear polystyrene-stabilized PdO nanoparticles (PS-PdONPs) were prepared by thermal decomposition of Pd(OAc) 2 in the presence of polystyrene. X-ray...
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StartPage 9067
SubjectTerms Acids
Catalysis
Metal Nanoparticles - chemistry
Microscopy, Electron, Transmission
Mizoroki-Heck reaction
Molecular Structure
Nanoparticles
Palladium
Palladium - chemistry
PdO nanoparticles
polystyrene
Polystyrenes - chemistry
Potassium
Spectrum Analysis - methods
water
Water - chemistry
X-Ray Diffraction
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Title Linear polystyrene-stabilized PdO nanoparticle-catalyzed Mizoroki-Heck reactions in water
URI https://www.ncbi.nlm.nih.gov/pubmed/22033141
https://www.proquest.com/docview/1531595841
https://pubmed.ncbi.nlm.nih.gov/PMC6264568
https://doaj.org/article/ae48d7aa55ce45888a2b539e480d622c
Volume 16
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