Linear polystyrene-stabilized PdO nanoparticle-catalyzed Mizoroki-Heck reactions in water

Linear polystyrene-stabilized PdO nanoparticles (PS-PdONPs) were prepared by thermal decomposition of Pd(OAc)(2) in the presence of polystyrene. X-ray diffraction (XRD) and transmission electron microscopy (TEM) indicated the production of PdO nanoparticles. The loading of palladium was determined b...

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Published inMolecules (Basel, Switzerland) Vol. 16; no. 11; pp. 9067 - 9076
Main Authors Ohtaka, Atsushi, Yamaguchi, Tomohiro, Teratani, Takuto, Shimomura, Osamu, Nomura, Ryôki
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 27.10.2011
MDPI
Subjects
Acids
Catalysis
Metal Nanoparticles - chemistry
Microscopy, Electron, Transmission
Mizoroki-Heck reaction
Molecular Structure
Nanoparticles
Palladium
Palladium - chemistry
PdO nanoparticles
polystyrene
Polystyrenes - chemistry
Potassium
Spectrum Analysis - methods
water
Water - chemistry
X-Ray Diffraction
Japan
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Summary:Linear polystyrene-stabilized PdO nanoparticles (PS-PdONPs) were prepared by thermal decomposition of Pd(OAc)(2) in the presence of polystyrene. X-ray diffraction (XRD) and transmission electron microscopy (TEM) indicated the production of PdO nanoparticles. The loading of palladium was determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). PS-PdONPs exhibited high catalytic activity for Mizoroki-Heck reactions under air in water and could be recycled without loss of activity.
ISSN:1420-3049
1420-3049
DOI:10.3390/molecules16119067