Self-Assembly of Functional Molecules into 1D Crystalline Nanostructures

• Published in: Advanced materials (Weinheim) Vol. 27; no. 6; pp. 985 - 1013
• Main Authors: Guo, Yanbing, Xu, Liang, Liu, Huibiao, Li, Yongjun, Che, Chi-Ming, Li, Yuliang
• Format: Journal Article
• Language: English
• Published: Germany Blackwell Publishing Ltd 01.02.2015
• Subjects: Carrier mobility; Crystal structure; Crystalline Nanostructures; Devices; Functional Molecules; Infusion; Miniature; Molecular structure; Nanostructure; One-Dimensional Nanostructures; Self assembly; Stability; One-Dimensional Nanostructures; Self-assembly; Crystalline Nanostructures; Functional Molecules
• ISSN: 0935-9648; 1521-4095
• DOI: 10.1002/adma.201403846

Self‐assembled functional nanoarchitectures are employed as important nanoscale building blocks for advanced materials and smart miniature devices to fulfill the increasing needs of high materials usage efficiency, low energy consumption, and high‐performance devices. One‐dimensional (1D) crystalline nanostructures, especially molecule‐composed crystalline nanostructures, attract significant attention due to their fascinating infusion structure and functionality which enables the easy tailoring of organic molecules with excellent carrier mobility and crystal stability. In this review, we discuss the recent progress of 1D crystalline self‐assembled nanostructures of functional molecules, which include both a small molecule‐derived and a polymer‐based crystalline nanostructure. The basic principles of the molecular structure design and the process engineering of 1D crystalline nanostructures are also discussed. The molecular building blocks, self‐assembly structures, and their applications in optical, electrical, and photoelectrical devices are overviewed and we give a brief outlook on crucial issues that need to be addressed in future research endeavors. Recent progress in self‐assembled 1D crystalline nanostructures of functional molecules is discussed, with both small‐molecule‐based crystalline nano structures and functional‐polymer self‐assembled 1D nanostructures. The molecular building blocks, the selfassembled structures, and applications in optical, electrical, and photoelectrical devices are overviewed and a brief outlook on crucial issues that need to be addressed in future research endeavors is given .