Towards Wireless Detection of Surface Modification of Silicon Nanowires by an RF Approach

• Published in: Nanomaterials (Basel, Switzerland) Vol. 12; no. 23; p. 4237
• Main Authors: Requena, Florian, Ahoulou, Samuel, Barbot, Nicolas, Kaddour, Darine, Nedelec, Jean-Marie, Baron, Thierry, Perret, Etienne
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 28.11.2022; MDPI
• Subjects: Backscattering; Chemical Sciences; Grafting; Humidity; humidity dependency; Identification and classification; Material chemistry; Methods; Nanoparticles; Nanotechnology; Nanowires; or physical chemistry; Permeability; physicochemical characterization; Properties; Radar; RF characterization; Scanning electron microscopy; Sensors; Silicon; silicon nanowires; Spectrum analysis; surface functionalization; Theoretical and; Topography; X-rays; France; radar; silicon nanowires; surface functionalization; physicochemical characterization; humidity dependency; temperature dependency; wireless measurement; RF characterization
• ISSN: 2079-4991; 2079-4991
• DOI: 10.3390/nano12234237

This paper shows the possibility to detect the presence of grafted molecules on the surface of silicon nanowires with a wireless RF radar approach based on the measurement of the backscattered signal of a resonant structure on which the nanowires are deposited. The measured resonance frequency allows the determination of the intrinsic properties related to temperature and humidity variations, which can be related to the presence of the grafted molecules. Several functionalizations of nanowires have been realized and characterized. For the first time, an RF approach is used to detect significant differences related to the presence of grafted molecules on the surface of nanowires. In addition to detecting their presence, the obtained results show the potential of the radar approach to identify the type of functionalization of nanowires. A set of six different grafted molecules (including octadecyltrichlorosilane, ethynylpyrene, N3) was tested and correctly separated with the proposed approach. Various measurements of the same samples showed a good repeatability which made the approach compatible with the possibility of differentiating the molecules with each other by radar reading. Moreover, discussions about the application of such functionalizations are made to increase the sensibility of sensors using a radar approach.