Tandem Synthesis of Photoactive Benzodifuran Moieties in the Formation of Microporous Organic Networks

Tiny pores: Benzodifuran moieties were introduced into microporous organic networks (MONs) through a tandem process consisting of Sonogashira coupling of 1,3,5‐triethynylbenzene and 2,5‐diiodo‐1,4‐hydroquinone and intramolecular cyclization. The resultant benzodifuran‐containing MON showed promising...

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Published inAngewandte Chemie International Edition Vol. 52; no. 24; pp. 6228 - 6232
Main Authors Kang, Narae, Park, Ji Hoon, Ko, Kyoung Chul, Chun, Jiseul, Kim, Eunchul, Shin, Hee-Won, Lee, Sang Moon, Kim, Hae Jin, Ahn, Tae Kyu, Lee, Jin Yong, Son, Seung Uk
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 10.06.2013
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
Amines
benzodifuran
Conversion
cross-coupling
Imines
Joining
microporous materials
Networks
photocatalyst
Porosity
Resultants
Synthesis
tandem synthesis
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Summary:Tiny pores: Benzodifuran moieties were introduced into microporous organic networks (MONs) through a tandem process consisting of Sonogashira coupling of 1,3,5‐triethynylbenzene and 2,5‐diiodo‐1,4‐hydroquinone and intramolecular cyclization. The resultant benzodifuran‐containing MON showed promising photocatalytic activities in the oxidative conversion of primary amines into imines.
Bibliography:NRF of Korea - No. NRF-2012-1040282; No. NRF-2007-0056343
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ArticleID:ANIE201300655
This work was supported by grants NRF-2012-045064 (Midcareer Researcher Program) and R31-2008-10029 (WCU program) through NRF of Korea. J.H.P. thanks for grant NRF-2012-1040282 (Priority Research Centers Program). J.Y.L. acknowledges grant NRF-2007-0056343.
This work was supported by grants NRF‐2012‐045064 (Midcareer Researcher Program) and R31‐2008‐10029 (WCU program) through NRF of Korea. J.H.P. thanks for grant NRF‐2012‐1040282 (Priority Research Centers Program). J.Y.L. acknowledges grant NRF‐2007‐0056343.
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201300655