Highly Selective Detection of Nitro Explosives by a Luminescent Metal-Organic Framework

TNP can't hide from MOF: A three‐dimensional fluorescent metal–organic framework (MOF), [Cd(NDC)0.5(PCA)]⋅Gx, can be used for the detection of 2,4,6‐trinitrophenol (TNP). The MOF exhibits high selectivity towards TNP, even in the presence of other nitro explosives in aqueous and organic solutio...

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Published inAngewandte Chemie International Edition Vol. 52; no. 10; pp. 2881 - 2885
Main Authors Nagarkar, Sanjog S., Joarder, Biplab, Chaudhari, Abhijeet K., Mukherjee, Soumya, Ghosh, Sujit K.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 04.03.2013
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
Electrostatics
Explosives
fluorescence
Hides
Metal-organic frameworks
Selectivity
sensors
Three dimensional
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Summary:TNP can't hide from MOF: A three‐dimensional fluorescent metal–organic framework (MOF), [Cd(NDC)0.5(PCA)]⋅Gx, can be used for the detection of 2,4,6‐trinitrophenol (TNP). The MOF exhibits high selectivity towards TNP, even in the presence of other nitro explosives in aqueous and organic solutions, owing to electron‐ and energy‐transfer mechanisms and electrostatic interactions.
Bibliography:istex:57B87A69A61D68B6752E3BD17F761054BF39750F
We are grateful to IISER Pune and DST (GAP/DST/CHE-12-0083) for financial support. We also thank HEMRL, Pune for TNT and RDX samples. We acknowledge Dr. Partha Hazra and group for valuable discussions during our fluorescence studies.
DST - No. GAP/DST/CHE-12-0083
ArticleID:ANIE201208885
IISER Pune
ark:/67375/WNG-H094C8B9-7
We are grateful to IISER Pune and DST (GAP/DST/CHE‐12‐0083) for financial support. We also thank HEMRL, Pune for TNT and RDX samples. We acknowledge Dr. Partha Hazra and group for valuable discussions during our fluorescence studies.
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201208885