Facile Deposition of Multicolored Electrochromic Metal-Organic Framework Thin Films

Metal–organic frameworks: The solvothermal reaction of Zn2+ ions and bis‐ (pyrazolyl)naphthalene diimide readily affords strongly adhering, electroactive metal–organic framework thin films on conductive glass substrates (see picture). Electrochemical cycling of these films followed by in situ UV/Vis...

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Published inAngewandte Chemie International Edition Vol. 52; no. 50; pp. 13377 - 13381
Main Authors Wade, Casey R., Li, Minyuan, Dincă, Mircea
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 09.12.2013
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
Cycles
Deposition
Diimide
electrochemistry
electrochromic materials
Electrochromism
Glass
Metal-organic frameworks
naphthalene diimide
Pictures
Spectroscopy
Thin films
naphthalene diimide
electrochemistry
electrochromic materials
metal-organic frameworks
thin films
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Summary:Metal–organic frameworks: The solvothermal reaction of Zn2+ ions and bis‐ (pyrazolyl)naphthalene diimide readily affords strongly adhering, electroactive metal–organic framework thin films on conductive glass substrates (see picture). Electrochemical cycling of these films followed by in situ UV/Vis spectroscopy reveals striking multicolored electrochromic responses.
Bibliography:U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences - No. DE-SC0006937
MIT-Hayashi Fund
This work was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under award number DE-SC0006937. This work also made use of the MRSEC Shared Experimental Facilities at MIT, supported in part by the NSF under award number DMR-0819762. M.D. thanks 3M for summer funding from a non-tenured faculty award and the MIT-Hayashi Fund for a travel grant.
istex:D407F5F8AC2AE586AAC222B36E90BC63CDA2547E
ArticleID:ANIE201306162
NSF - No. DMR-0819762
ark:/67375/WNG-NRS6GGCB-T
This work was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under award number DE‐SC0006937. This work also made use of the MRSEC Shared Experimental Facilities at MIT, supported in part by the NSF under award number DMR‐0819762. M.D. thanks 3M for summer funding from a non‐tenured faculty award and the MIT‐Hayashi Fund for a travel grant.
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201306162