Desymmetrization Catalyzed by Transition-Metal Complexes: Enantioselective Formation of Silicon-Stereogenic Silanes
Prochiral silanes: Recent work has demonstrated the powerful potential of enantioselective desymmetrization catalyzed by transition‐metal complexes in the stereoselective formation of silicon‐stereogenic silanes. These methods offer new possibilities for asymmetric synthesis of any functionalized ch...
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| Published in | Angewandte Chemie International Edition Vol. 51; no. 52; pp. 12932 - 12934 |
|---|---|
| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag
21.12.2012
WILEY‐VCH Verlag Wiley Subscription Services, Inc |
| Edition | International ed. in English |
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| Abstract | Prochiral silanes: Recent work has demonstrated the powerful potential of enantioselective desymmetrization catalyzed by transition‐metal complexes in the stereoselective formation of silicon‐stereogenic silanes. These methods offer new possibilities for asymmetric synthesis of any functionalized chiral silanes that possess tetraorganosilicon stereocenters. |
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| AbstractList | Prochiral silanes: Recent work has demonstrated the powerful potential of enantioselective desymmetrization catalyzed by transition-metal complexes in the stereoselective formation of silicon-stereogenic silanes. These methods offer new possibilities for asymmetric synthesis of any functionalized chiral silanes that possess tetraorganosilicon stereocenters. Prochiral silanes: recent work has demonstrated the powerful potential of enantioselective desymmetrization catalyzed by transition-metal complexes in the stereoselective formation of silicon-stereogenic silanes. These methods offer new possibilities for asymmetric synthesis of any functionalized chiral silanes that possess tetraorganosilicon stereocenters.Prochiral silanes: recent work has demonstrated the powerful potential of enantioselective desymmetrization catalyzed by transition-metal complexes in the stereoselective formation of silicon-stereogenic silanes. These methods offer new possibilities for asymmetric synthesis of any functionalized chiral silanes that possess tetraorganosilicon stereocenters. |
| Author | Xu, Li-Wen |
| Author_xml | – sequence: 1 givenname: Li-Wen surname: Xu fullname: Xu, Li-Wen email: liwenxu@hznu.edu.cn, licpxulw@yahoo.com organization: Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou (P. R. China) |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/23255401$$D View this record in MEDLINE/PubMed |
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| Snippet | Prochiral silanes: Recent work has demonstrated the powerful potential of enantioselective desymmetrization catalyzed by transition‐metal complexes in the... Prochiral silanes: recent work has demonstrated the powerful potential of enantioselective desymmetrization catalyzed by transition-metal complexes in the... Prochiral silanes: Recent work has demonstrated the powerful potential of enantioselective desymmetrization catalyzed by transition-metal complexes in the... |
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| SubjectTerms | asymmetric synthesis Asymmetry desymmetrization Formations Metal complexes Silanes Silicon silicon-stereogenic silanes Synthesis transition metals |
| Title | Desymmetrization Catalyzed by Transition-Metal Complexes: Enantioselective Formation of Silicon-Stereogenic Silanes |
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