Desymmetrization Catalyzed by Transition-Metal Complexes: Enantioselective Formation of Silicon-Stereogenic Silanes

Prochiral silanes: Recent work has demonstrated the powerful potential of enantioselective desymmetrization catalyzed by transition‐metal complexes in the stereoselective formation of silicon‐stereogenic silanes. These methods offer new possibilities for asymmetric synthesis of any functionalized ch...

Full description

Saved in:
Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 51; no. 52; pp. 12932 - 12934
Main Author Xu, Li-Wen
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 21.12.2012
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
asymmetric synthesis
Asymmetry
desymmetrization
Formations
Metal complexes
Silanes
Silicon
silicon-stereogenic silanes
Synthesis
transition metals
Online AccessGet full text

Cover

More Information
Summary:Prochiral silanes: Recent work has demonstrated the powerful potential of enantioselective desymmetrization catalyzed by transition‐metal complexes in the stereoselective formation of silicon‐stereogenic silanes. These methods offer new possibilities for asymmetric synthesis of any functionalized chiral silanes that possess tetraorganosilicon stereocenters.
Bibliography:ArticleID:ANIE201207932
National Natural Science Founder of China - No. 20973051; No. 21173064
ark:/67375/WNG-3RFSLF9B-5
istex:7079760F4AD39DA672F1EEA589F76CA169C65201
This work was supported by the National Natural Science Founder of China (20973051 and 21173064).
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
content type line 23
ISSN:1433-7851
1521-3773
1521-3773
DOI:10.1002/anie.201207932