Palladium-Catalyzed Intermolecular Asymmetric Allylic Dearomatization Reaction of Naphthol Derivatives

Baring all: The title reaction provides β‐naphthalenones bearing an all‐carbon quaternary center in good to excellent yields, as well as excellent chemo‐ and enantioselectivity (see scheme).

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Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 52; no. 38; pp. 10056 - 10059
Main Authors Zhuo, Chun-Xiang, You, Shu-Li
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 16.09.2013
WILEY‐VCH Verlag
Wiley
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
allylic dearomatization
arenes
asymmetric catalysis
Asymmetry
Bearing
Chemistry
Chemistry, Multidisciplinary
Derivatives
Naphthol
palladium
Physical Sciences
Science & Technology
synthetic methods
ENANTIOSELECTIVE SYNTHESIS
OXIDATIVE DEAROMATIZATION
allylic dearomatization
BOND FORMATION
asymmetric catalysis
WORKING MODEL
QUATERNARY STEREOCENTER
arenes
CONSTRUCTION
BIFUNCTIONAL CATALYST
palladium
ALKYLATION REACTIONS
PHENOL DEAROMATIZATION
C-ALLYLATION
synthetic methods
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Summary:Baring all: The title reaction provides β‐naphthalenones bearing an all‐carbon quaternary center in good to excellent yields, as well as excellent chemo‐ and enantioselectivity (see scheme).
Bibliography:NSFC - No. 20923005; No. 21025209; No. 21121062
National Basic Research Program of China - No. 2010CB833300
Chinese Academy of Sciences
istex:92C0982EF079CF1FAB7FCB7141A38A71E8145C82
ArticleID:ANIE201304591
ark:/67375/WNG-XBG71C9D-N
We thank the NSFC (20923005, 21025209, 21121062), the National Basic Research Program of China (973 Program 2010CB833300), and the Chinese Academy of Sciences for generous financial support.
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201304591