Seasonal features and origins of carbonaceous aerosols at Syowa Station, coastal Antarctica

• Published in: Atmospheric chemistry and physics Vol. 19; no. 11; pp. 7817 - 7837
• Main Authors: Hara, Keiichiro, Sudo, Kengo, Ohnishi, Takato, Osada, Kazuo, Yabuki, Masanori, Shiobara, Masataka, Yamanouchi, Takashi
• Format: Journal Article
• Language: English
• Published: Katlenburg-Lindau Copernicus GmbH 12.06.2019; Copernicus Publications
• Subjects: Aerosols; Air masses; Analysis; Antarctic zone; Atmospheric research; Biomass burning; Black carbon; Boundary layers; Burning; Carbon; Chemical transport; Combustion; Computer simulation; Detection; Fossil fuels; Fuel combustion; Long-range transport; Measurement; Organic chemistry; Origins; Polar environments; Simulation; Trajectory analysis; Transport; Transport processes; Troposphere; Antarctica; South America; Africa
• ISSN: 1680-7324; 1680-7316; 1680-7324
• DOI: 10.5194/acp-19-7817-2019

We have measured black carbon (BC) concentrations at Syowa Station, Antarctica, since February 2005. The measured BC concentrations in 2005–2016 were corrected to equivalent BC (EBC) concentrations using Weingartner's method. Seasonal features of EBC concentrations, long-range transport from mid-latitudes to the Antarctic coast, and their origins were characterized. Results show that daily median EBC concentrations were below the detection limit (0.2 ng m−3) to 63.8 ng m−3 at Syowa Station (median, 1.8 ng m−3; mean, 2.7 ng m−3 during the measurement period of February 2005–December 2016). Although seasonal features and year-to-year variations in EBC concentrations were observed, no long-term trend of EBC concentrations was clear during our measurement period. Seasonal features of EBC concentrations showed a spring maximum during September–October at Syowa Station. To elucidate EBC transport processes, origins, and the potential source area (PSA), we compared EBC data to backward trajectory analysis and chemical transport model simulation. From comparison with backward trajectory, high EBC concentrations were found in air masses from the marine boundary layer. This finding implies that transport via the marine boundary layer was the most important transport pathway to EBC concentrations at Antarctic coasts. Some EBC was supplied to the Antarctic region by transport via the upper free troposphere. Chemical transport model simulation demonstrated that the most important origins and PSA of EBC at Syowa Station were biomass burning in South America and southern Africa. Fossil fuel combustion in South America and southern Africa also have important contributions. The absorption Ångström exponent (AAE) showed clear seasonal features with 0.5–1.0 during April–October and maximum (1.0–1.5) in December–February. The AAE features might be associated with organic aerosols and mixing states of EBC.