Realization of unpinned two-dimensional dirac states in antimony atomic layers

• Published in: Nature communications Vol. 13; no. 1; p. 4603
• Main Authors: Lu, Qiangsheng, Cook, Jacob, Zhang, Xiaoqian, Chen, Kyle Y., Snyder, Matthew, Nguyen, Duy Tung, Reddy, P. V. Sreenivasa, Qin, Bingchao, Zhan, Shaoping, Zhao, Li-Dong, Kowalczyk, Pawel J., Brown, Simon A., Chiang, Tai-Chang, Yang, Shengyuan A., Chang, Tay-Rong, Bian, Guang
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 06.08.2022; Nature Publishing Group; Nature Portfolio
• Subjects: 639/766/119/2792/4128; 639/766/119/995; Antimony; Brillouin zones; Cones; electronic materials; electronic properties; Graphene; Humanities and Social Sciences; Lattice strain; MATERIALS SCIENCE; Metalloids; Momentum; multidisciplinary; Phosphorene; Science; Science (multidisciplinary); Symmetry; Thin films; Topological insulators; Two dimensional materials
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/s41467-022-32327-8

Two-dimensional (2D) Dirac states with linear dispersion have been observed in graphene and on the surface of topological insulators. 2D Dirac states discovered so far are exclusively pinned at high-symmetry points of the Brillouin zone, for example, surface Dirac states at Γ ¯ in topological insulators Bi 2 Se(Te) 3 and Dirac cones at K and K ′ points in graphene. The low-energy dispersion of those Dirac states are isotropic due to the constraints of crystal symmetries. In this work, we report the observation of novel 2D Dirac states in antimony atomic layers with phosphorene structure. The Dirac states in the antimony films are located at generic momentum points. This unpinned nature enables versatile ways such as lattice strains to control the locations of the Dirac points in momentum space. In addition, dispersions around the unpinned Dirac points are highly anisotropic due to the reduced symmetry of generic momentum points. The exotic properties of unpinned Dirac states make antimony atomic layers a new type of 2D Dirac semimetals that are distinct from graphene. In graphene and on the surfaces of many topological insulators, the Dirac cones are pinned to high symmetry points in reciprocal space. Here, the authors report that the Dirac cones in atomically-thin Sb layers occur at generic reciprocal-space points which can be tuned by lattice strain.