Diarylamine/diarylnitroxide cycle: quantum chemical and electrochemical estimation

• Published in: Heliyon Vol. 5; no. 10; p. e02735
• Main Authors: Levitskiy, Oleg A., Sentyurin, Vyacheslav V., Magdesieva, Tatiana V.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.10.2019; Elsevier
• Subjects: cleavage (chemistry); Diaryl nitroxides; Electrochemical bond cleavage; Electrochemistry; Electrode reactions; electrodes; energy; moieties; Organic chemistry; oxygen; quantum mechanics; Redox materials; Specific solvation; Theoretical chemistry; Electrochemical bond cleavage; Organic chemistry; Electrode reactions; Diaryl nitroxides; Specific solvation; Electrochemistry; Theoretical chemistry; Redox materials
• ISSN: 2405-8440; 2405-8440
• DOI: 10.1016/j.heliyon.2019.e02735

Possibility for diarylamine/diarylnitroxide cycling via electrochemical N–O bond formation/bond breaking processes was considered using quantum-chemical and electrochemical methods. It was shown that electrochemically reduced diarylnitroxides undergo fast N–O bond cleavage in the presence of oxophilic Li ions. The possible reaction scheme was suggested. In contrast, in the presence of Na+ salts, aminoxyl anions are stable and can be considered as possible anodic redox active material in energy storage systems utilizing Na+ ions migration. Direct oxygenation of diarylaminyl radicals with dioxygen yielding diarylnitroxide is not feasible; multiple competing routes involving the aromatic moiety are observed instead. The results obtained shed light on possibilities and limitations for functioning of nitroxide-based redox active electrode materials. Electrochemistry; Organic chemistry; Theoretical Chemistry; electrochemical bond cleavage; diaryl nitroxides; redox materials; electrode reactions; specific solvation