Investigation of phosphate adsorption onto ferrihydrite by X-ray Photoelectron Spectroscopy

• Published in: Journal of colloid and interface science Vol. 407; pp. 95 - 101
• Main Authors: Mallet, M., Barthélémy, K., Ruby, C., Renard, A., Naille, S.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier Inc 01.10.2013; Elsevier
• Subjects: Adsorption; anions; chemical bonding; chemical composition; Chemical Sciences; Chemistry; Chromatography, Liquid; electrolytes; energy; Exact sciences and technology; Ferric Compounds - chemistry; Ferrihydrite; General and physical chemistry; Hydrogen-Ion Concentration; ionic strength; Iron; Kinetics; Mathematical models; nitrates; Phosphate; Phosphates; Phosphates - chemistry; Photoelectron Spectroscopy - methods; Sorption; sorption isotherms; Spectra; sulfates; Surface chemistry; Surface physical chemistry; Thermodynamics; X-ray Photoelectron Spectroscopy; Ferrihydrite; X-ray Photoelectron Spectroscopy; Adsorption; Phosphate; Phosphates; Photoelectron spectrometry
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1016/j.jcis.2013.06.049

[Display omitted] •Combined XPS surface analysis and solution data to investigate phosphate sorption.•Low pH conditions and high ionic strength both favor phosphate sorption.•Evidence of chemical bonding between iron and phosphate at the ferrihydrite surface. The objective of this study was to characterize phosphate adsorption onto synthetic 2-lines ferrihydrite using surface analysis by X-ray Photoelectron Spectroscopy and batch experiments. Surface analysis of ferrihydrite samples before phosphate sorption gives very reproducible Fe:O surface ratios of (1:3±0.1). Phosphate sorption onto ferrihydrite was investigated by means of pH, initial phosphate concentration, and ionic strength effects. Additionally, potential background electrolyte influence on phosphate adsorption was also determined. Phosphate uptake by ferrihydrite significantly increases with decreasing pH, with a maximum uptake of 104.8mgPO4g−1 obtained at pH=4. Phosphate removal increases with the enhancement of ionic strength in agreement with the formation of inner-sphere complexes. The presence of chloride, nitrate, and sulfate showed no competing effect on phosphate removal efficiency. Sorption kinetics follow a pseudo-second order model (R2>0.99) and the Freundlich isotherm model adequately describes sorption (R2=0.995). The careful examination of high resolution Fe 2p, O 1s, and P 2p spectra before and after phosphate sorption allows the characterization of the modifications occurring onto the ferrihydrite surface. The binding energy of the P 2p peak agrees well with that observed in Fe-PO4 compounds. Additionally, binding energy shifts in the Fe 2p spectra combined to variations in the relative intensity of the components in the high resolution O 1s spectra illustrate well the formation of chemical bonding between iron and phosphate anions at the ferrihydrite surface.