Porous Carbon‐Hosted Atomically Dispersed Iron–Nitrogen Moiety as Enhanced Electrocatalysts for Oxygen Reduction Reaction in a Wide Range of pH

• Published in: Small (Weinheim an der Bergstrasse, Germany) Vol. 14; no. 12; pp. e1703118 - n/a
• Main Authors: Fu, Shaofang, Zhu, Chengzhou, Su, Dong, Song, Junhua, Yao, Siyu, Feng, Shuo, Engelhard, Mark H., Du, Dan, Lin, Yuehe
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 01.03.2018; Wiley
• Subjects: Catalysis; Catalysts; Electrocatalysts; ENERGY PLANNING, POLICY AND ECONOMY; Fe-N-C electrocatalysts; Metal organic frameworks; Nanoengineering; Nanotechnology; Nitrogen; nonprecious metal nanocatalysts; oxygen reduction reaction; Oxygen reduction reactions; Platinum; Pyrolysis; single-atom catalysts; single-atom catalysts; nonprecious metal nanocatalysts; oxygen reduction reaction; Fe-N-C electrocatalysts; metal-organic frameworks
• ISSN: 1613-6810; 1613-6829; 1613-6829
• DOI: 10.1002/smll.201703118

As one of the alternatives to replace precious metal catalysts, transition‐metal–nitrogen–carbon (M–N–C) electrocatalysts have attracted great research interest due to their low cost and good catalytic activities. Despite nanostructured M–N–C catalysts can achieve good electrochemical performances, they are vulnerable to aggregation and insufficient catalytic sites upon continuous catalytic reaction. In this work, metal–organic frameworks derived porous single‐atom electrocatalysts (SAEs) were successfully prepared by simple pyrolysis procedure without any further posttreatment. Combining the X‐ray absorption near‐edge spectroscopy and electrochemical measurements, the SAEs have been identified with superior oxygen reduction reaction (ORR) activity and stability compared with Pt/C catalysts in alkaline condition. More impressively, the SAEs also show excellent ORR electrocatalytic performance in both acid and neutral media. This study of nonprecious catalysts provides new insights on nanoengineering catalytically active sites and porous structures for nonprecious metal ORR catalysis in a wide range of pH. Fe‐doped metal organic framework‐derived nonprecious nanocatalysts with single active sites are obtained by a simple pyrolysis procedure. The obtained Fe–N–C single‐atom electrocatalysts possess superior oxygen reduction reaction performance in a wide range of pH.