Catalytic Fehling's Reaction: An Efficient Aerobic Oxidation of Aldehyde Catalyzed by Copper in Water
The first example of homogeneous copper‐catalyzed aerobic oxidation of aldehydes is reported. This method utilizes atmospheric oxygen as the sole oxidant, proceeds under extremely mild aqueous conditions, and covers a wide range of various functionalized aldehydes. Chromatography is generally not ne...
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| Published in | Angewandte Chemie International Edition Vol. 55; no. 36; pp. 10806 - 10810 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
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WEINHEIM
Blackwell Publishing Ltd
26.08.2016
Wiley Wiley Subscription Services, Inc |
| Edition | International ed. in English |
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| Abstract | The first example of homogeneous copper‐catalyzed aerobic oxidation of aldehydes is reported. This method utilizes atmospheric oxygen as the sole oxidant, proceeds under extremely mild aqueous conditions, and covers a wide range of various functionalized aldehydes. Chromatography is generally not necessary for product purification.
Without ‘Fehl ’: The first example of homogeneous copper‐catalyzed aerobic oxidation of aldehydes is reported. This method utilizes atmospheric oxygen as the sole oxidant, proceeds under extremely mild aqueous conditions, and covers a wide range of various functionalized aldehydes. Chromatography is generally not necessary for product purification. |
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| AbstractList | The first example of homogeneous copper‐catalyzed aerobic oxidation of aldehydes is reported. This method utilizes atmospheric oxygen as the sole oxidant, proceeds under extremely mild aqueous conditions, and covers a wide range of various functionalized aldehydes. Chromatography is generally not necessary for product purification.
Without ‘Fehl ’: The first example of homogeneous copper‐catalyzed aerobic oxidation of aldehydes is reported. This method utilizes atmospheric oxygen as the sole oxidant, proceeds under extremely mild aqueous conditions, and covers a wide range of various functionalized aldehydes. Chromatography is generally not necessary for product purification. The first example of homogeneous copper-catalyzed aerobic oxidation of aldehydes is reported. This method utilizes atmospheric oxygen as the sole oxidant, proceeds under extremely mild aqueous conditions, and covers a wide range of various functionalized aldehydes. Chromatography is generally not necessary for product purification. The first example of homogeneous copper-catalyzed aerobic oxidation of aldehydes is reported. This method utilizes atmospheric oxygen as the sole oxidant, proceeds under extremely mild aqueous conditions, and covers a wide range of various functionalized aldehydes. Chromatography is generally not necessary for product purification.The first example of homogeneous copper-catalyzed aerobic oxidation of aldehydes is reported. This method utilizes atmospheric oxygen as the sole oxidant, proceeds under extremely mild aqueous conditions, and covers a wide range of various functionalized aldehydes. Chromatography is generally not necessary for product purification. |
| Author | Li, Chao-Jun Liu, Mingxin |
| Author_xml | – sequence: 1 givenname: Mingxin surname: Liu fullname: Liu, Mingxin organization: Department of Chemistry and FRQNT Center for Green Chemistry and Catalysis, McGill University, Quebec, H3A 0B8, Montreal, Canada – sequence: 2 givenname: Chao-Jun surname: Li fullname: Li, Chao-Jun email: cj.li@mcgill.ca organization: Department of Chemistry and FRQNT Center for Green Chemistry and Catalysis, McGill University, Quebec, H3A 0B8, Montreal, Canada |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/27505714$$D View this record in MEDLINE/PubMed |
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| Keywords | ALCOHOLS ACETYLACETONATE COMPLEXES homogeneous catalysis oxidation reaction mechanisms NHC copper MOLECULAR-OXYGEN CARBOXYLIC-ACIDS |
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| Snippet | The first example of homogeneous copper‐catalyzed aerobic oxidation of aldehydes is reported. This method utilizes atmospheric oxygen as the sole oxidant,... The first example of homogeneous copper-catalyzed aerobic oxidation of aldehydes is reported. This method utilizes atmospheric oxygen as the sole oxidant,... |
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| SubjectTerms | Aldehydes Catalysis Chemistry Chemistry, Multidisciplinary Chromatography Copper homogeneous catalysis Oxidation Oxidizing agents Oxygen Physical Sciences Purification reaction mechanisms Science & Technology |
| Title | Catalytic Fehling's Reaction: An Efficient Aerobic Oxidation of Aldehyde Catalyzed by Copper in Water |
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