Conversion of Dinitrogen to Nitriles at a Multinuclear Titanium Framework
Activation and functionalization of N2: A mixed diimide/dinitride tetranuclear titanium complex formed by activation of dinitrogen served as a unique platform for the synthesis of nitriles (see picture). Functional groups such as aromatic C−X (X=Cl, Br, I) bonds, nitro groups, and ammonia‐sensitive...
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| Published in | Angewandte Chemie International Edition Vol. 55; no. 40; pp. 12316 - 12320 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
WEINHEIM
Blackwell Publishing Ltd
26.09.2016
Wiley Wiley Subscription Services, Inc |
| Edition | International ed. in English |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Activation and functionalization of N2: A mixed diimide/dinitride tetranuclear titanium complex formed by activation of dinitrogen served as a unique platform for the synthesis of nitriles (see picture). Functional groups such as aromatic C−X (X=Cl, Br, I) bonds, nitro groups, and ammonia‐sensitive aldehyde and chloromethyl moieties were compatible with the synthetic method. |
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| AbstractList | Activation and functionalization of N2 : A mixed diimide/dinitride tetranuclear titanium complex formed by activation of dinitrogen served as a unique platform for the synthesis of nitriles. Functional groups such as aromatic C-X (X=Cl, Br, I) bonds, nitro groups, and ammonia-sensitive aldehyde and chloromethyl moieties were compatible with the synthetic method. Activation and functionalization of N2: A mixed diimide/dinitride tetranuclear titanium complex formed by activation of dinitrogen served as a unique platform for the synthesis of nitriles (see picture). Functional groups such as aromatic C−X (X=Cl, Br, I) bonds, nitro groups, and ammonia‐sensitive aldehyde and chloromethyl moieties were compatible with the synthetic method. Activation and functionalization of N2: A mixed diimide/dinitride tetranuclear titanium complex formed by activation of dinitrogen served as a unique platform for the synthesis of nitriles (see picture). Functional groups such as aromatic C-X (X=Cl, Br, I) bonds, nitro groups, and ammonia-sensitive aldehyde and chloromethyl moieties were compatible with the synthetic method. At present, ammonia (NH3), produced by the energy-intensive Haber-Bosch process, is the only nitrogen source for the industrial preparation of nitrogen-containing organic products. Although the activation and functionalization of dinitrogen (N-2) under milder conditions have received much recent interest, studies on the direct use of N-2 as a feedstock for organic synthesis are still in their infancy. Herein we report the synthesis of nitriles using titanium-activated nitrogen species as a nitrogen source. We have found that a mixed diimide/dinitride tetranuclear titanium complex generated by N-2 activation serves as a unique platform for the synthesis of nitriles through reaction with acid chlorides. This protocol features simple reaction condition (60 degrees C in benzene), no requirement for extra reagents, and unprecedented functional group tolerance (compatible with aromatic C-X (X = Cl, Br, I) bonds, nitro group, and ammonia-sensitive aldehyde and chloromethyl moieties). |
| Author | Shima, Takanori Guru, Murali Mohan Hou, Zhaomin |
| Author_xml | – sequence: 1 givenname: Murali Mohan surname: Guru fullname: Guru, Murali Mohan organization: Advanced Catalysis Research Group, RIKEN, Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, 351-0198, Saitama, Japan – sequence: 2 givenname: Takanori surname: Shima fullname: Shima, Takanori organization: Advanced Catalysis Research Group, RIKEN, Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, 351-0198, Saitama, Japan – sequence: 3 givenname: Zhaomin surname: Hou fullname: Hou, Zhaomin email: houz@riken.jp organization: Advanced Catalysis Research Group, RIKEN, Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, 351-0198, Saitama, Japan |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/27611111$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1002/ange.201409676 10.1021/ja9921219 10.1021/ja9943288 10.1002/1521-3773(20021004)41:19<3709::AID-ANIE3709>3.0.CO;2-U 10.1038/nature02274 10.1021/ja510317h 10.1002/1521-3757(20021004)114:19<3861::AID-ANGE3861>3.0.CO;2-4 10.1002/anie.201502293 10.1021/ja502759d 10.1126/science.279.5350.540 10.1021/ja056408j 10.1021/cr60316a001 10.1002/anie.201405673 10.1039/C4CC09563D 10.1021/ic5015972 10.1002/adsc.200303081 10.1002/1521-3757(20011015)113:20<4025::AID-ANGE4025>3.0.CO;2-5 10.1021/ja0538841 10.1038/nchem.477 10.1016/j.jorganchem.2004.05.053 10.1021/ja2042595 10.1126/science.1143078 10.1002/anie.201307097 10.1021/ol900716q 10.1021/ar800061g 10.1016/j.tetlet.2014.01.032 10.1021/acs.accounts.5b00213 10.1002/ange.201502293 10.1002/ange.201405673 10.1021/ja002707r 10.1002/ange.201600790 10.1039/c1cs15004a 10.1021/ja106848y 10.1002/ange.200903648 10.1021/ja066090a 10.1126/science.1238663 10.1021/ja050387b 10.1126/science.275.5305.1445 10.1021/ja072248v 10.1002/anie.201409676 10.1021/ja045566s 10.1002/ange.201307097 10.1039/b305774g 10.1021/ja505309j 10.1126/science.268.5212.861 10.1002/anie.201600790 10.1002/1521-3773(20011015)40:20<3907::AID-ANIE3907>3.0.CO;2-# 10.1002/anie.200903648 10.1039/c2cc17634c 10.1126/science.1211906 10.1021/ja405477m 10.1038/NCHEM.477 10.1039/c4cc09563d |
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| Copyright | 2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Keywords | hydrides SIDE-ON NN BOND ACTIVATION titanium COORDINATED DINITROGEN CLEAVAGE FUNCTIONALIZATION N-2 nitriles organometallics PARTIAL HYDROGENATION dinitrogen activation END-ON BONDING MODE |
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| References | Y. Lee, F. T. Sloane, G. Blondin, K. A. Abboud, R. Garcia-Serres, L. J. Murray, Angew. Chem. Int. Ed. 2015, 54, 1499 T. Miyazaki, H. Tanaka, Y. Tanabe, M. Yuki, K. Nakajima, K. Yoshizawa, Y. Nishibayashi, Angew. Chem. Int. Ed. 2014, 53, 11488 A. Caselli, E. Solari, R. Scopelliti, C. Floriani, N. Re, C. Rizzoli, A. Chiesi-Villa, J. Am. Chem. Soc. 2000, 122, 3652 M. D. Fryzuk, J. B. Love, S. J. Rettig, V. G. Young, Science 1997, 275, 1445. I. Klopsch, M. Finger, C. Würtele, B. Milde, D. B. Werz, S. Schneider, J. Am. Chem. Soc. 2014, 136, 6881. K. Ueda, Y. Sato, M. Mori, J. Am. Chem. Soc. 2000, 122, 10722 K. Searles, P. J. Carroll, C.-H. Chen, M. Pink, D. J. Mindiola, Chem. Commun. 2015, 51, 3526 M. D. Fryzuk, B. A. MacKay, S. A. Johnson, B. O. Patrick, Angew. Chem. Int. Ed. 2002, 41, 3709 Angew. Chem. 2002, 114, 3861 Angew. Chem. 2015, 127, 1519 J. J. Curley, E. L. Sceats, C. C. Cummins, J. Am. Chem. Soc. 2006, 128, 14036 G. B. Nikiforov, I. Vidyaratne, S. Gambarotta, I. Korobkov, Angew. Chem. Int. Ed. 2009, 48, 7415 Angew. Chem. 2009, 121, 7551 Angew. Chem. 2016, 128, 4864 D. J. Knobloch, E. Lobkovsky, P. J. Chirik, J. Am. Chem. Soc. 2010, 132, 15340 H. Henderickx, G. Kwakkenbos, A. Peters, J. van der Spoel, K. de Vries, Chem. Commun. 2003, 2050 The unidentified paramagnetic species might possibly be a further dehydrogenated trinitride monoimide species like [(Cp′Ti)4(μ3-N)3(μ3-NH)]. For more details, see the Supporting Information, and see also: J. Caballo, M. González-Moreiras, M. Greño, M. Mena, A. Pérez-Redondo, C. Yélamos, Inorg. Chem. 2014, 53, 8851. G. K. B. Clentsmith, V. M. E. Bates, P. B. Hitchcock, F. G. N. Cloke, J. Am. Chem. Soc. 1999, 121, 10444. C. E. Laplaza, C. C. Cummins, Science 1995, 268, 861. S. F. McWilliams, P. L. Holland, Acc. Chem. Res. 2015, 48, 2059 E. Solari, C. Da Silva, B. Lacono, J. Hesschenbrouck, C. Rizzoli, R. Scopelliti, C. Floriani, Angew. Chem. Int. Ed. 2001, 40, 3907 P. Anbarasan, T. Schareina, M. Beller, Chem. Soc. Rev. 2011, 40, 5049. M. D. Fryzuk, Acc. Chem. Res. 2009, 42, 127 Y. Nishibayashi, S. Iwai, M. Hidai, Science 1998, 279, 540 S. P. Semproni, P. J. Chirik, Angew. Chem. Int. Ed. 2013, 52, 12965 J. Clayden, N. Greeves, S. Warren, Organic Chemistry, 2nd ed., Oxford University Press, New York, 2001, p. 284 S. Zhou, K. Junge, D. Addis, S. Das, M. Beller, Org. Lett. 2009, 11, 2461. J. A. Pool, W. H. Bernskoetter, P. J. Chirik, J. Am. Chem. Soc. 2004, 126, 14326 M. P. Shaver, M. D. Fryzuk, Adv. Synth. Catal. 2003, 345, 1061 I. Klopsch, M. Kinauer, M. Finger, C. Würtele, S. Schneider, Angew. Chem. Int. Ed. 2016, 55, 4786 Angew. Chem. 2013, 125, 13203 M. M. Rodriguez, E. Bill, W. W. Brennessel, P. L. Holland, Science 2011, 334, 780 A. J. Keane, W. S. Farrell, B. L. Yonke, P. Y. Zavalij, L. R. Sita, Angew. Chem. Int. Ed. 2015, 54, 10220 R. C. Larock, Comprehensive Organic Transformations, VCH, New York, 1989, p. 819. M. Hirotsu, P. P. Fontaine, A. Epshteyn, P. Y. Zavalij, L. R. Sita, J. Am. Chem. Soc. 2007, 129, 9284 Y. Ishida, H. Kawaguchi, J. Am. Chem. Soc. 2014, 136, 16990 A. J. Keane, B. L. Yonke, M. Hirotsu, P. Y. Zavalij, L. R. Sita, J. Am. Chem. Soc. 2014, 136, 9906 J. Chatt, J. R. Dilworth, R. L. Richards, Chem. Rev. 1978, 78, 589. V. Smil, Enriching the Earth, MIT Press, Cambridge, MA, 2004. M. Mori, J. Organomet. Chem. 2004, 689, 4210 D. J. Knobloch, E. Lobkovsky, P. J. Chirik, Nat. Chem. 2010, 2, 30 S. P. Semproni, E. Lobkovsky, P. J. Chirik, J. Am. Chem. Soc. 2011, 133, 10406 Q. Wen, J. Jin, L. Zhang, Y. Luo, P. Lu, Y. Wang, Tetrahedron Lett. 2014, 55, 1271 Angew. Chem. 2014, 126, 11672 W. H. Bernskoetter, E. Lobkovsky, P. J. Chirik, J. Am. Chem. Soc. 2005, 127, 14051 J. A. Pool, E. Lobkovsky, P. J. Chirik, Nature 2004, 427, 527 J. S. Figueroa, N. A. Piro, C. R. Clough, C. C. Cummins, J. Am. Chem. Soc. 2006, 128, 940 S. P. Semproni, P. J. Chirik, J. Am. Chem. Soc. 2013, 135, 11373 W. H. Bernskoetter, J. A. Pool, E. Lobkovsky, P. J. Chirik, J. Am. Chem. Soc. 2005, 127, 7901 T. J. Hebden, R. R. Schrock, M. K. Takase, P. Müller, Chem. Commun. 2012, 48, 1851 Angew. Chem. 2001, 113, 4025 Angew. Chem. 2015, 127, 10358 T. Shima, S. Hu, G. Luo, X. Kang, Y. Luo, Z. Hou, Science 2013, 340, 1549 P. Avenier, M. Taoufik, A. Lesage, X. Solans-Monfort, A. Baudouin, A. de Mallmann, L. Veyre, J.-M. Basset, O. Eisenstein, L. Emsley, E. A. Quadrelli, Science 2007, 317, 1056 2014 2014; 53 126 2011; 334 2007; 129 2004; 126 2009; 42 1978; 78 2009 2009; 48 121 2015; 51 1997; 275 2011; 40 1999; 121 2004 1998; 279 2003 2013; 340 2004; 427 2004; 689 2014; 136 2011; 133 2013 2013; 52 125 2009; 11 2015; 48 2007; 317 2016 2016; 55 128 2001 2002 2002; 41 114 2005; 127 2010; 132 2015 2015; 54 127 2013; 135 1995; 268 2000; 122 2012; 48 2010; 2 2003; 345 2001 2001; 40 113 2006; 128 2014; 55 1989 2014; 53 e_1_2_2_24_2 e_1_2_2_47_2 e_1_2_2_6_1 e_1_2_2_22_2 e_1_2_2_49_2 e_1_2_2_20_2 e_1_2_2_41_2 e_1_2_2_28_3 e_1_2_2_8_2 e_1_2_2_28_2 e_1_2_2_43_2 e_1_2_2_45_2 e_1_2_2_26_1 e_1_2_2_13_2 e_1_2_2_36_2 e_1_2_2_36_3 e_1_2_2_11_2 e_1_2_2_38_2 e_1_2_2_51_2 e_1_2_2_30_2 e_1_2_2_19_1 e_1_2_2_30_3 e_1_2_2_51_3 e_1_2_2_53_1 e_1_2_2_17_2 e_1_2_2_32_2 e_1_2_2_55_1 e_1_2_2_15_2 e_1_2_2_34_2 e_1_2_2_13_3 e_1_2_2_23_2 e_1_2_2_48_2 e_1_2_2_5_2 e_1_2_2_21_2 e_1_2_2_3_1 e_1_2_2_40_2 e_1_2_2_29_2 e_1_2_2_42_2 e_1_2_2_7_2 e_1_2_2_9_1 e_1_2_2_27_3 e_1_2_2_42_3 e_1_2_2_27_2 e_1_2_2_44_2 e_1_2_2_46_1 e_1_2_2_25_2 Clayden J. (e_1_2_2_4_2) 2001 Smil V. (e_1_2_2_1_1) 2004 e_1_2_2_12_2 e_1_2_2_37_2 e_1_2_2_10_2 e_1_2_2_39_2 e_1_2_2_54_1 e_1_2_2_18_2 e_1_2_2_31_2 e_1_2_2_52_2 e_1_2_2_16_3 e_1_2_2_56_1 e_1_2_2_16_2 e_1_2_2_33_2 Larock R. C. (e_1_2_2_2_1) 1989 e_1_2_2_14_2 e_1_2_2_35_2 e_1_2_2_50_1 Hebden, TJ (WOS:000299112500002) 2012; 48 Anbarasan, P (WOS:000295037400013) 2011; 40 Keane, AJ (WOS:000339228200028) 2014; 136 Pool, JA (WOS:000188721800037) 2004; 427 Ishida, Y (WOS:000346544200011) 2014; 136 Miyazaki, T (WOS:000343870400012) 2014; 53 Semproni, SP (WOS:000293149800022) 2011; 133 Larock, R. C. (000384713700029.29) 1989 Semproni, S. P. (000384713700029.46) 2013; 125 Hirotsu, M (WOS:000248281100019) 2007; 129 Klopsch, I (WOS:000336078400027) 2014; 136 Nikiforov, G. B. (000384713700029.37) 2009; 121 Nikiforov, GB (WOS:000270436700025) 2009; 48 Wen, QD (WOS:000331509800001) 2014; 55 Bernskoetter, WH (WOS:000229447700042) 2005; 127 Semproni, SP (WOS:000322752900071) 2013; 135 Fryzuk, M. D. (000384713700029.12) 2002; 114 Fryzuk, MD (WOS:000178609900046) 2002; 41 Nishibayashi, Y (WOS:000071616000039) 1998; 279 LAPLAZA, CE (WOS:A1995QX85000034) 1995; 268 Keane, AJ (WOS:000360216800027) 2015; 54 Knobloch, DJ (WOS:000283621700048) 2010; 132 Avenier, P (WOS:000248946700037) 2007; 317 Solari, E (WOS:000171698000041) 2001; 40 Lee, Y (WOS:000348713900015) 2015; 54 Caballo, J (WOS:000341229600005) 2014; 53 Shaver, MP (WOS:000185881500005) 2003; 345 Mori, M (WOS:000225673500025) 2004; 689 McWilliams, SF (WOS:000358556400029) 2015; 48 Rodriguez, MM (WOS:000296849600039) 2011; 334 Lee, Y. (000384713700029.31) 2015; 127 CHATT, J (WOS:A1978FX42600001) 1978; 78 Keane, A. J. (000384713700029.22) 2015; 127 Henderickx, H (WOS:000184346100028) 2003 Clayden, J. (000384713700029.8) 2001 Miyazaki, T. (000384713700029.33) 2014; 126 Ueda, K (WOS:000165205000034) 2000; 122 Knobloch, DJ (WOS:000272806800012) 2010; 2 Bernskoetter, WH (WOS:000232413300061) 2005; 127 Fryzuk, MD (WOS:000262616700013) 2009; 42 Zhou, SL (WOS:000266546300060) 2009; 11 Curley, JJ (WOS:000241519600033) 2006; 128 Searles, K (WOS:000349325400007) 2015; 51 Pool, JA (WOS:000224964500012) 2004; 126 Caselli, A (WOS:000086729500011) 2000; 122 Figueroa, JS (WOS:000234815000059) 2006; 128 Klopsch, I. (000384713700029.25) 2016; 128 Semproni, SP (WOS:000327410300036) 2013; 52 Klopsch, I (WOS:000373615900030) 2016; 55 Clentsmith, GKB (WOS:000083719800035) 1999; 121 Fryzuk, MD (WOS:A1997WM08100034) 1997; 275 Shima, T (WOS:000321007000035) 2013; 340 Smil, V. (000384713700029.49) 2004 |
| References_xml | – reference: Angew. Chem. 2001, 113, 4025; – reference: Y. Lee, F. T. Sloane, G. Blondin, K. A. Abboud, R. Garcia-Serres, L. J. Murray, Angew. Chem. Int. Ed. 2015, 54, 1499; – reference: T. Shima, S. Hu, G. Luo, X. Kang, Y. Luo, Z. Hou, Science 2013, 340, 1549; – reference: K. Ueda, Y. Sato, M. Mori, J. Am. Chem. Soc. 2000, 122, 10722; – reference: M. Hirotsu, P. P. Fontaine, A. Epshteyn, P. Y. Zavalij, L. R. Sita, J. Am. Chem. Soc. 2007, 129, 9284; – reference: M. D. Fryzuk, B. A. MacKay, S. A. Johnson, B. O. Patrick, Angew. Chem. Int. Ed. 2002, 41, 3709; – reference: I. Klopsch, M. Kinauer, M. Finger, C. Würtele, S. Schneider, Angew. Chem. Int. Ed. 2016, 55, 4786; – reference: D. J. Knobloch, E. Lobkovsky, P. J. Chirik, Nat. Chem. 2010, 2, 30; – reference: J. Clayden, N. Greeves, S. Warren, Organic Chemistry, 2nd ed., Oxford University Press, New York, 2001, p. 284; – reference: Q. Wen, J. Jin, L. Zhang, Y. Luo, P. Lu, Y. Wang, Tetrahedron Lett. 2014, 55, 1271; – reference: T. Miyazaki, H. Tanaka, Y. Tanabe, M. Yuki, K. Nakajima, K. Yoshizawa, Y. Nishibayashi, Angew. Chem. Int. Ed. 2014, 53, 11488; – reference: Angew. Chem. 2015, 127, 1519; – reference: R. C. Larock, Comprehensive Organic Transformations, VCH, New York, 1989, p. 819. – reference: E. Solari, C. Da Silva, B. Lacono, J. Hesschenbrouck, C. Rizzoli, R. Scopelliti, C. Floriani, Angew. Chem. Int. Ed. 2001, 40, 3907; – reference: A. Caselli, E. Solari, R. Scopelliti, C. Floriani, N. Re, C. Rizzoli, A. Chiesi-Villa, J. Am. Chem. Soc. 2000, 122, 3652; – reference: P. Avenier, M. Taoufik, A. Lesage, X. Solans-Monfort, A. Baudouin, A. de Mallmann, L. Veyre, J.-M. Basset, O. Eisenstein, L. Emsley, E. A. Quadrelli, Science 2007, 317, 1056; – reference: H. Henderickx, G. Kwakkenbos, A. Peters, J. van der Spoel, K. de Vries, Chem. Commun. 2003, 2050; – reference: Y. Nishibayashi, S. Iwai, M. Hidai, Science 1998, 279, 540; – reference: S. P. Semproni, P. J. Chirik, J. Am. Chem. Soc. 2013, 135, 11373; – reference: J. A. Pool, E. Lobkovsky, P. J. Chirik, Nature 2004, 427, 527; – reference: J. Chatt, J. R. Dilworth, R. L. Richards, Chem. Rev. 1978, 78, 589. – reference: A. J. Keane, W. S. Farrell, B. L. Yonke, P. Y. Zavalij, L. R. Sita, Angew. Chem. Int. Ed. 2015, 54, 10220; – reference: S. P. Semproni, E. Lobkovsky, P. J. Chirik, J. Am. Chem. Soc. 2011, 133, 10406; – reference: W. H. Bernskoetter, J. A. Pool, E. Lobkovsky, P. J. Chirik, J. Am. Chem. Soc. 2005, 127, 7901; – reference: J. S. Figueroa, N. A. Piro, C. R. Clough, C. C. Cummins, J. Am. Chem. Soc. 2006, 128, 940; – reference: J. A. Pool, W. H. Bernskoetter, P. J. Chirik, J. Am. Chem. Soc. 2004, 126, 14326; – reference: W. H. Bernskoetter, E. Lobkovsky, P. J. Chirik, J. Am. Chem. Soc. 2005, 127, 14051; – reference: Angew. Chem. 2014, 126, 11672; – reference: Angew. Chem. 2015, 127, 10358; – reference: I. Klopsch, M. Finger, C. Würtele, B. Milde, D. B. Werz, S. Schneider, J. Am. Chem. Soc. 2014, 136, 6881. – reference: M. D. Fryzuk, J. B. Love, S. J. Rettig, V. G. Young, Science 1997, 275, 1445. – reference: A. J. Keane, B. L. Yonke, M. Hirotsu, P. Y. Zavalij, L. R. Sita, J. Am. Chem. Soc. 2014, 136, 9906; – reference: Angew. Chem. 2002, 114, 3861; – reference: J. J. Curley, E. L. Sceats, C. C. Cummins, J. Am. Chem. Soc. 2006, 128, 14036; – reference: M. D. Fryzuk, Acc. Chem. Res. 2009, 42, 127; – reference: S. F. McWilliams, P. L. Holland, Acc. Chem. Res. 2015, 48, 2059; – reference: M. M. Rodriguez, E. Bill, W. W. Brennessel, P. L. Holland, Science 2011, 334, 780; – reference: M. Mori, J. Organomet. Chem. 2004, 689, 4210; – reference: M. P. Shaver, M. D. Fryzuk, Adv. Synth. Catal. 2003, 345, 1061; – reference: S. P. Semproni, P. J. Chirik, Angew. Chem. Int. Ed. 2013, 52, 12965; – reference: D. J. Knobloch, E. Lobkovsky, P. J. Chirik, J. Am. Chem. Soc. 2010, 132, 15340; – reference: Angew. Chem. 2009, 121, 7551; – reference: S. Zhou, K. Junge, D. Addis, S. Das, M. Beller, Org. Lett. 2009, 11, 2461. – reference: Angew. Chem. 2013, 125, 13203; – reference: T. J. Hebden, R. R. Schrock, M. K. Takase, P. Müller, Chem. Commun. 2012, 48, 1851; – reference: Angew. Chem. 2016, 128, 4864; – reference: P. Anbarasan, T. Schareina, M. Beller, Chem. Soc. Rev. 2011, 40, 5049. – reference: K. Searles, P. J. Carroll, C.-H. Chen, M. Pink, D. J. Mindiola, Chem. Commun. 2015, 51, 3526; – reference: The unidentified paramagnetic species might possibly be a further dehydrogenated trinitride monoimide species like [(Cp′Ti)4(μ3-N)3(μ3-NH)]. For more details, see the Supporting Information, and see also: J. Caballo, M. González-Moreiras, M. Greño, M. Mena, A. Pérez-Redondo, C. Yélamos, Inorg. Chem. 2014, 53, 8851. – reference: C. E. Laplaza, C. C. Cummins, Science 1995, 268, 861. – reference: Y. Ishida, H. Kawaguchi, J. Am. Chem. Soc. 2014, 136, 16990; – reference: G. B. Nikiforov, I. Vidyaratne, S. Gambarotta, I. Korobkov, Angew. Chem. Int. Ed. 2009, 48, 7415; – reference: V. Smil, Enriching the Earth, MIT Press, Cambridge, MA, 2004. – reference: G. K. B. Clentsmith, V. M. E. Bates, P. B. Hitchcock, F. G. N. Cloke, J. Am. Chem. Soc. 1999, 121, 10444. – volume: 279 start-page: 540 year: 1998 publication-title: Science – volume: 121 start-page: 10444 year: 1999 publication-title: J. Am. Chem. Soc. – volume: 317 start-page: 1056 year: 2007 publication-title: Science – volume: 78 start-page: 589 year: 1978 publication-title: Chem. Rev. – start-page: 2050 year: 2003 publication-title: Chem. Commun. – volume: 55 start-page: 1271 year: 2014 publication-title: Tetrahedron Lett. – volume: 40 start-page: 5049 year: 2011 publication-title: Chem. Soc. Rev. – volume: 132 start-page: 15340 year: 2010 publication-title: J. Am. Chem. Soc. – volume: 42 start-page: 127 year: 2009 publication-title: Acc. Chem. Res. – volume: 275 start-page: 1445 year: 1997 publication-title: Science – volume: 135 start-page: 11373 year: 2013 publication-title: J. Am. Chem. Soc. – volume: 268 start-page: 861 year: 1995 publication-title: Science – volume: 136 start-page: 16990 year: 2014 publication-title: J. Am. Chem. Soc. – volume: 136 start-page: 6881 year: 2014 publication-title: J. Am. Chem. Soc. – volume: 133 start-page: 10406 year: 2011 publication-title: J. Am. Chem. Soc. – volume: 345 start-page: 1061 year: 2003 publication-title: Adv. Synth. Catal. – volume: 689 start-page: 4210 year: 2004 publication-title: J. Organomet. Chem. – volume: 11 start-page: 2461 year: 2009 publication-title: Org. Lett. – volume: 48 start-page: 2059 year: 2015 publication-title: Acc. Chem. Res. – volume: 122 start-page: 10722 year: 2000 publication-title: J. Am. Chem. Soc. – volume: 122 start-page: 3652 year: 2000 publication-title: J. Am. Chem. Soc. – volume: 427 start-page: 527 year: 2004 publication-title: Nature – volume: 54 127 start-page: 10220 10358 year: 2015 2015 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 128 start-page: 940 year: 2006 publication-title: J. Am. Chem. Soc. – volume: 51 start-page: 3526 year: 2015 publication-title: Chem. Commun. – volume: 52 125 start-page: 12965 13203 year: 2013 2013 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 53 126 start-page: 11488 11672 year: 2014 2014 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 340 start-page: 1549 year: 2013 publication-title: Science – volume: 54 127 start-page: 1499 1519 year: 2015 2015 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 48 121 start-page: 7415 7551 year: 2009 2009 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 55 128 start-page: 4786 4864 year: 2016 2016 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 127 start-page: 14051 year: 2005 publication-title: J. Am. Chem. Soc. – volume: 126 start-page: 14326 year: 2004 publication-title: J. Am. Chem. Soc. – volume: 128 start-page: 14036 year: 2006 publication-title: J. Am. Chem. Soc. – year: 2004 – volume: 41 114 start-page: 3709 3861 year: 2002 2002 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 48 start-page: 1851 year: 2012 publication-title: Chem. Commun. – start-page: 819 year: 1989 – volume: 136 start-page: 9906 year: 2014 publication-title: J. Am. Chem. Soc. – volume: 127 start-page: 7901 year: 2005 publication-title: J. Am. Chem. Soc. – volume: 2 start-page: 30 year: 2010 publication-title: Nat. Chem. – volume: 53 start-page: 8851 year: 2014 publication-title: Inorg. Chem. – volume: 334 start-page: 780 year: 2011 publication-title: Science – start-page: 284 year: 2001 – volume: 40 113 start-page: 3907 4025 year: 2001 2001 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 129 start-page: 9284 year: 2007 publication-title: J. Am. Chem. Soc. – ident: e_1_2_2_46_1 – ident: e_1_2_2_27_3 doi: 10.1002/ange.201409676 – ident: e_1_2_2_18_2 doi: 10.1021/ja9921219 – ident: e_1_2_2_54_1 – ident: e_1_2_2_17_2 doi: 10.1021/ja9943288 – ident: e_1_2_2_42_2 doi: 10.1002/1521-3773(20021004)41:19<3709::AID-ANIE3709>3.0.CO;2-U – ident: e_1_2_2_24_2 doi: 10.1038/nature02274 – ident: e_1_2_2_29_2 doi: 10.1021/ja510317h – ident: e_1_2_2_42_3 doi: 10.1002/1521-3757(20021004)114:19<3861::AID-ANGE3861>3.0.CO;2-4 – ident: e_1_2_2_28_2 doi: 10.1002/anie.201502293 – ident: e_1_2_2_52_2 doi: 10.1021/ja502759d – ident: e_1_2_2_44_2 doi: 10.1126/science.279.5350.540 – ident: e_1_2_2_48_2 doi: 10.1021/ja056408j – ident: e_1_2_2_45_2 doi: 10.1021/cr60316a001 – ident: e_1_2_2_3_1 – ident: e_1_2_2_13_2 doi: 10.1002/anie.201405673 – ident: e_1_2_2_11_2 doi: 10.1039/C4CC09563D – start-page: 819 volume-title: Comprehensive Organic Transformations year: 1989 ident: e_1_2_2_2_1 – ident: e_1_2_2_53_1 doi: 10.1021/ic5015972 – ident: e_1_2_2_40_2 doi: 10.1002/adsc.200303081 – ident: e_1_2_2_55_1 – ident: e_1_2_2_16_3 doi: 10.1002/1521-3757(20011015)113:20<4025::AID-ANGE4025>3.0.CO;2-5 – ident: e_1_2_2_22_2 doi: 10.1021/ja0538841 – ident: e_1_2_2_6_1 – ident: e_1_2_2_33_2 doi: 10.1038/nchem.477 – ident: e_1_2_2_9_1 – ident: e_1_2_2_39_2 doi: 10.1016/j.jorganchem.2004.05.053 – ident: e_1_2_2_32_2 doi: 10.1021/ja2042595 – ident: e_1_2_2_21_2 doi: 10.1126/science.1143078 – ident: e_1_2_2_30_2 doi: 10.1002/anie.201307097 – ident: e_1_2_2_5_2 doi: 10.1021/ol900716q – ident: e_1_2_2_35_2 doi: 10.1021/ar800061g – ident: e_1_2_2_7_2 doi: 10.1016/j.tetlet.2014.01.032 – ident: e_1_2_2_10_2 doi: 10.1021/acs.accounts.5b00213 – ident: e_1_2_2_28_3 doi: 10.1002/ange.201502293 – ident: e_1_2_2_13_3 doi: 10.1002/ange.201405673 – volume-title: Enriching the Earth year: 2004 ident: e_1_2_2_1_1 – ident: e_1_2_2_43_2 doi: 10.1021/ja002707r – ident: e_1_2_2_51_3 doi: 10.1002/ange.201600790 – ident: e_1_2_2_8_2 doi: 10.1039/c1cs15004a – ident: e_1_2_2_34_2 doi: 10.1021/ja106848y – ident: e_1_2_2_36_3 doi: 10.1002/ange.200903648 – ident: e_1_2_2_47_2 doi: 10.1021/ja066090a – ident: e_1_2_2_20_2 doi: 10.1126/science.1238663 – ident: e_1_2_2_38_2 doi: 10.1021/ja050387b – ident: e_1_2_2_25_2 doi: 10.1126/science.275.5305.1445 – ident: e_1_2_2_26_1 – ident: e_1_2_2_37_2 doi: 10.1021/ja072248v – ident: e_1_2_2_50_1 – ident: e_1_2_2_27_2 doi: 10.1002/anie.201409676 – ident: e_1_2_2_56_1 – ident: e_1_2_2_23_2 doi: 10.1021/ja045566s – ident: e_1_2_2_30_3 doi: 10.1002/ange.201307097 – ident: e_1_2_2_41_2 doi: 10.1039/b305774g – ident: e_1_2_2_12_2 doi: 10.1021/ja505309j – ident: e_1_2_2_49_2 doi: 10.1126/science.268.5212.861 – ident: e_1_2_2_51_2 doi: 10.1002/anie.201600790 – ident: e_1_2_2_19_1 – ident: e_1_2_2_16_2 doi: 10.1002/1521-3773(20011015)40:20<3907::AID-ANIE3907>3.0.CO;2-# – ident: e_1_2_2_36_2 doi: 10.1002/anie.200903648 – ident: e_1_2_2_14_2 doi: 10.1039/c2cc17634c – ident: e_1_2_2_15_2 doi: 10.1126/science.1211906 – start-page: 284 volume-title: Organic Chemistry year: 2001 ident: e_1_2_2_4_2 – ident: e_1_2_2_31_2 doi: 10.1021/ja405477m – volume: 53 start-page: 11488 year: 2014 ident: WOS:000343870400012 article-title: Cleavage and Formation of Molecular Dinitrogen in a Single System Assisted by Molybdenum Complexes Bearing Ferrocenyldiphosphine publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201405673 – volume: 125 start-page: 13203 year: 2013 ident: 000384713700029.46 publication-title: Angew. Chem. – start-page: 284 year: 2001 ident: 000384713700029.8 publication-title: Organic Chemistry – volume: 132 start-page: 15340 year: 2010 ident: WOS:000283621700048 article-title: Functionalization of Hafnium Oxamidide Complexes Prepared from CO-Induced N2 Cleavage publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja106848y – volume: 114 start-page: 3861 year: 2002 ident: 000384713700029.12 publication-title: Angew. Chem. – volume: 340 start-page: 1549 year: 2013 ident: WOS:000321007000035 article-title: Dinitrogen Cleavage and Hydrogenation by a Trinuclear Titanium Polyhydride Complex publication-title: SCIENCE doi: 10.1126/science.1238663 – volume: 279 start-page: 540 year: 1998 ident: WOS:000071616000039 article-title: Bimetallic system for nitrogen fixation:: Ruthenium-assisted protonation of coordinated N2 on tungsten with H2 publication-title: SCIENCE – volume: 126 start-page: 11672 year: 2014 ident: 000384713700029.33 publication-title: Angew. Chem. – volume: 127 start-page: 7901 year: 2005 ident: WOS:000229447700042 article-title: Dinitrogen functionalization with terminal alkynes, amines, and hydrazines promoted by [(η5-C5Me4H)2Zr]2(μ2,η2 η2-N2):: Observation of side-on and end-on diazenido complexes in the reduction of N2 to hydrazine publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja050387b – volume: 55 start-page: 4786 year: 2016 ident: WOS:000373615900030 article-title: Conversion of Dinitrogen into Acetonitrile under Ambient Conditions publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201600790 – volume: 128 start-page: 14036 year: 2006 ident: WOS:000241519600033 article-title: A cycle for organic nitrile synthesis via dinitrogen cleavage publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja066090a – volume: 127 start-page: 10358 year: 2015 ident: 000384713700029.22 publication-title: Angew. Chem. – volume: 128 start-page: 940 year: 2006 ident: WOS:000234815000059 article-title: A nitridoniobium(V) reagent that effects acid chloride to organic nitrile conversion: Synthesis via heterodinuclear (Nb/Mo) dinitrogen cleavage, mechanistic insights, and recycling publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja056408j – volume: 334 start-page: 780 year: 2011 ident: WOS:000296849600039 article-title: N2 Reduction and Hydrogenation to Ammonia by a Molecular Iron-Potassium Complex publication-title: SCIENCE doi: 10.1126/science.1211906 – volume: 52 start-page: 12965 year: 2013 ident: WOS:000327410300036 article-title: Activation of Dinitrogen-Derived Hafnium Nitrides for Nucleophilic N-C Bond Formation with a Terminal Isocyanate publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201307097 – volume: 345 start-page: 1061 year: 2003 ident: WOS:000185881500005 article-title: Activation of molecular nitrogen:: Coordination, cleavage and functionalization of N2 mediated by metal complexes publication-title: ADVANCED SYNTHESIS & CATALYSIS doi: 10.1002/adsc.200303081 – volume: 53 start-page: 8851 year: 2014 ident: WOS:000341229600005 article-title: Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane publication-title: INORGANIC CHEMISTRY doi: 10.1021/ic5015972 – volume: 40 start-page: 3907 year: 2001 ident: WOS:000171698000041 article-title: Photochemical activation of the NN bond in a dimolybdenum-dinitrogen complex:: Formation of a molybdenum nitride publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION – volume: 136 start-page: 9906 year: 2014 ident: WOS:000339228200028 article-title: Fine-Tuning the Energy Barrier for Metal-Mediated Dinitrogen NN Bond Cleavage publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja505309j – volume: 48 start-page: 7415 year: 2009 ident: WOS:000270436700025 article-title: Titanium-Promoted Dinitrogen Cleavage, Partial Hydrogenation, and Silylation publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.200903648 – volume: 317 start-page: 1056 year: 2007 ident: WOS:000248946700037 article-title: Dinitrogen dissociation on an isolated surface tantalum atom publication-title: SCIENCE doi: 10.1126/science.1143078 – volume: 78 start-page: 589 year: 1978 ident: WOS:A1978FX42600001 article-title: RECENT ADVANCES IN CHEMISTRY OF NITROGEN-FIXATION publication-title: CHEMICAL REVIEWS – volume: 122 start-page: 10722 year: 2000 ident: WOS:000165205000034 article-title: Incorporation of N2 and CO into organic molecules:: Amide formation by palladium-catalyzed carbonylation and nitrogenation publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY – volume: 55 start-page: 1271 year: 2014 ident: WOS:000331509800001 article-title: Copper-mediated cyanation reactions publication-title: TETRAHEDRON LETTERS doi: 10.1016/j.tetlet.2014.01.032 – volume: 2 start-page: 30 year: 2010 ident: WOS:000272806800012 article-title: Dinitrogen cleavage and functionalization by carbon monoxide promoted by a hafnium complex publication-title: NATURE CHEMISTRY doi: 10.1038/NCHEM.477 – volume: 275 start-page: 1445 year: 1997 ident: WOS:A1997WM08100034 article-title: Transformation of coordinated dinitrogen by reaction with dihydrogen and primary silanes publication-title: SCIENCE – year: 2004 ident: 000384713700029.49 publication-title: Enriching the Earth – volume: 48 start-page: 1851 year: 2012 ident: WOS:000299112500002 article-title: Cleavage of dinitrogen to yield a (t-BuPOCOP)molybdenum(IV) nitride publication-title: CHEMICAL COMMUNICATIONS doi: 10.1039/c2cc17634c – volume: 133 start-page: 10406 year: 2011 ident: WOS:000293149800022 article-title: Dinitrogen Silylation and Cleavage with a Hafnocene Complex publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja2042595 – start-page: 819 year: 1989 ident: 000384713700029.29 publication-title: Comprehensive Organic Transformations – volume: 51 start-page: 3526 year: 2015 ident: WOS:000349325400007 article-title: Niobium-nitrides derived from nitrogen splitting publication-title: CHEMICAL COMMUNICATIONS doi: 10.1039/c4cc09563d – volume: 122 start-page: 3652 year: 2000 ident: WOS:000086729500011 article-title: Dinitrogen rearranging over a metal-oxo surface and cleaving to nitride:: From the end-on to the side-on bonding mode, to the stepwise cleavage of the NN bonds assisted by NbIII-calix[4]arene publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY – volume: 121 start-page: 10444 year: 1999 ident: WOS:000083719800035 article-title: Reductive cleavage of dinitrogen by a vanadium diamidoamine complex:: The molecular structures of [V(Me3SiN{CH2CH2NSiMe3}2)(μ-N)]2 and K[V(Me3SiN{ CH2CH2NSiMe3}2)(μ-N)]2 publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY – volume: 427 start-page: 527 year: 2004 ident: WOS:000188721800037 article-title: Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex publication-title: NATURE doi: 10.1038/nature02274 – volume: 126 start-page: 14326 year: 2004 ident: WOS:000224964500012 article-title: On the origin of dinitrogen hydrogenation promoted by [(η5-C5Me4H)2Zr]2(μ2,η2,η2-N2) publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja045566s – volume: 135 start-page: 11373 year: 2013 ident: WOS:000322752900071 article-title: Synthesis of a Base-Free Hafnium Nitride from N2 Cleavage: A Versatile Platform for Dinitrogen Functionalization publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja405477m – volume: 54 start-page: 1499 year: 2015 ident: WOS:000348713900015 article-title: Dinitrogen Activation Upon Reduction of a Triiron(II) Complex publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201409676 – volume: 136 start-page: 16990 year: 2014 ident: WOS:000346544200011 article-title: Nitrogen Atom Transfer from a Dinitrogen-Derived Vanadium Nitride Complex to Carbon Monoxide and Isocyanide publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja510317h – volume: 48 start-page: 2059 year: 2015 ident: WOS:000358556400029 article-title: Dinitrogen Binding and Cleavage by Multinuclear Iron Complexes publication-title: ACCOUNTS OF CHEMICAL RESEARCH doi: 10.1021/acs.accounts.5b00213 – volume: 128 start-page: 4864 year: 2016 ident: 000384713700029.25 publication-title: Angew. Chem. – volume: 54 start-page: 10220 year: 2015 ident: WOS:000360216800027 article-title: Metal-Mediated Production of Isocyanates, R3EN=C=O from Dinitrogen, Carbon Dioxide, and R3ECl publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201502293 – volume: 129 start-page: 9284 year: 2007 ident: WOS:000248281100019 article-title: Dinitrogen activation at ambient temperatures:: New modes of H2 and PhSiH3 additions for an "End-on-bridged" [Ta(IV)]2(μ-η1:η1-N2) complex and for the bis(μ-nitrido) [Ta(V)(μ-N)]2 product derived from facile N=N bond cleavage publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja072248v – volume: 121 start-page: 7551 year: 2009 ident: 000384713700029.37 publication-title: Angew. Chem. – volume: 11 start-page: 2461 year: 2009 ident: WOS:000266546300060 article-title: A General and Convenient Catalytic Synthesis of Nitriles from Amides and Silanes publication-title: ORGANIC LETTERS doi: 10.1021/ol900716q – start-page: 2050 year: 2003 ident: WOS:000184346100028 article-title: Direct formation of an organonitrogen compound from a molybdenum nitrido species publication-title: CHEMICAL COMMUNICATIONS doi: 10.1039/b305774g – volume: 136 start-page: 6881 year: 2014 ident: WOS:000336078400027 article-title: Dinitrogen Splitting and Functionalization in the Coordination Sphere of Rhenium publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja502759d – volume: 42 start-page: 127 year: 2009 ident: WOS:000262616700013 article-title: Side-on End-on Bound Dinitrogen: An Activated Bonding Mode That Facilitates Functionalizing Molecular Nitrogen publication-title: ACCOUNTS OF CHEMICAL RESEARCH doi: 10.1021/ar800061g – volume: 40 start-page: 5049 year: 2011 ident: WOS:000295037400013 article-title: Recent developments and perspectives in palladium-catalyzed cyanation of aryl halides: synthesis of benzonitriles publication-title: CHEMICAL SOCIETY REVIEWS doi: 10.1039/c1cs15004a – volume: 689 start-page: 4210 year: 2004 ident: WOS:000225673500025 article-title: Activation of nitrogen for organic synthesis publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY doi: 10.1016/j.jorganchem.2004.05.053 – volume: 127 start-page: 1519 year: 2015 ident: 000384713700029.31 publication-title: Angew. Chem. – volume: 127 start-page: 14051 year: 2005 ident: WOS:000232413300061 article-title: Kinetics and mechanism of N2 hydrogenation in bis(cyclopentadienyl) zirconium complexes and dinitrogen functionalization by 1,2-addition of a saturated C-H bond publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja0538841 – volume: 41 start-page: 3709 year: 2002 ident: WOS:000178609900046 article-title: Hydroboration of coordinated dinitrogen:: A new reaction for the N2 ligand that results in its functionalization and cleavage publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION – volume: 268 start-page: 861 year: 1995 ident: WOS:A1995QX85000034 article-title: DINITROGEN CLEAVAGE BY A 3-COORDINATE MOLYBDENUM(III) COMPLEX publication-title: SCIENCE |
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| Snippet | Activation and functionalization of N2: A mixed diimide/dinitride tetranuclear titanium complex formed by activation of dinitrogen served as a unique platform... At present, ammonia (NH3), produced by the energy-intensive Haber-Bosch process, is the only nitrogen source for the industrial preparation of... Activation and functionalization of N2 : A mixed diimide/dinitride tetranuclear titanium complex formed by activation of dinitrogen served as a unique platform... |
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| SubjectTerms | Activation Ammonia Bonding Chemistry Chemistry, Multidisciplinary Compatibility Conversion Diimide dinitrogen activation Functional anatomy Functional groups hydrides Nitriles organometallics Physical Sciences Science & Technology Titanium |
| Title | Conversion of Dinitrogen to Nitriles at a Multinuclear Titanium Framework |
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