Conversion of Dinitrogen to Nitriles at a Multinuclear Titanium Framework

Activation and functionalization of N2: A mixed diimide/dinitride tetranuclear titanium complex formed by activation of dinitrogen served as a unique platform for the synthesis of nitriles (see picture). Functional groups such as aromatic C−X (X=Cl, Br, I) bonds, nitro groups, and ammonia‐sensitive...

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Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 55; no. 40; pp. 12316 - 12320
Main Authors Guru, Murali Mohan, Shima, Takanori, Hou, Zhaomin
Format Journal Article
LanguageEnglish
Published WEINHEIM Blackwell Publishing Ltd 26.09.2016
Wiley
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
Activation
Ammonia
Bonding
Chemistry
Chemistry, Multidisciplinary
Compatibility
Conversion
Diimide
dinitrogen activation
Functional anatomy
Functional groups
hydrides
Nitriles
organometallics
Physical Sciences
Science & Technology
Titanium
hydrides
SIDE-ON
NN BOND
ACTIVATION
titanium
COORDINATED DINITROGEN
CLEAVAGE
FUNCTIONALIZATION
N-2
nitriles
organometallics
PARTIAL HYDROGENATION
dinitrogen activation
END-ON
BONDING MODE
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Summary:Activation and functionalization of N2: A mixed diimide/dinitride tetranuclear titanium complex formed by activation of dinitrogen served as a unique platform for the synthesis of nitriles (see picture). Functional groups such as aromatic C−X (X=Cl, Br, I) bonds, nitro groups, and ammonia‐sensitive aldehyde and chloromethyl moieties were compatible with the synthetic method.
Bibliography:istex:A47EB67562980058DBFC9E47A92A6A57FD75D8BF
Japan Society for Promotion of Science (JSPS) - No. 21429201
National Science Foundation of China (NSFC)
ark:/67375/WNG-2GMGDVH6-D
ArticleID:ANIE201607426
KAKEN
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201607426