Conjugated nitrosoalkenes as Michael acceptors in carbon-carbon bond forming reactions: a review and perspective

Despite of their chemical instability and high reactivity, conjugated nitrosoalkenes are useful intermediates in target-oriented organic synthesis. The present review deals with carbon-carbon bond forming reactions involving Michael addition to α-nitrosoalkenes with a particular focus on recent deve...

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Published inBeilstein journal of organic chemistry Vol. 13; no. 1; pp. 2214 - 2234
Main Authors Boyko, Yaroslav Dmitrievich, Dorokhov, Valentin Sergeevich, Sukhorukov, Alexey Yu, Ioffe, Sema Leibovich
Format Journal Article
LanguageEnglish
Published Germany Beilstein-Institut zur Föerderung der Chemischen Wissenschaften 23.10.2017
Beilstein-Institut
Subjects
Carbon
carbon–carbon bond formation
Chemical bonds
Chemistry
Intermediates
Michael addition
nitrosoalkenes
oximes
Polymerization
Review
total synthesis
Michael addition
nitrosoalkenes
total synthesis
carbon–carbon bond formation
oximes
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Summary:Despite of their chemical instability and high reactivity, conjugated nitrosoalkenes are useful intermediates in target-oriented organic synthesis. The present review deals with carbon-carbon bond forming reactions involving Michael addition to α-nitrosoalkenes with a particular focus on recent developments in this methodology and its use in total synthesis.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-3
content type line 23
ObjectType-Review-1
ISSN:1860-5397
2195-951X
1860-5397
DOI:10.3762/bjoc.13.220