Longevity gene responsible for robust blue organic materials employing thermally activated delayed fluorescence

• Published in: Nature communications Vol. 14; no. 1; p. 3927
• Main Authors: Meng, Qing-Yu, Wang, Rui, Wang, Yi-Lei, Guo, Xing-Wei, Liu, Yu-Qi, Wen, Xue-Liang, Yao, Cheng-Yu, Qiao, Juan
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 03.07.2023; Nature Publishing Group; Nature Portfolio
• Subjects: 140/58; 639/301/1019/1020/1091; 639/638/440/949; Atomic energy levels; Chemical degradation; Chemistry; Degradation; Efficiency; Emitters; Energy; Energy consumption; Energy of dissociation; Fluorescence; Free energy; Heat of formation; Humanities and Social Sciences; Industrial development; Logarithms; Longevity; multidisciplinary; Organic materials; Robustness; Science; Science (multidisciplinary); Screening; Service life assessment; Stability; Triplet state
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/s41467-023-39697-7

The 3 rd -Gen OLED materials employing thermally-activated delayed fluorescence (TADF) combine advantages of first two for high-efficiency and low-cost devices. Though urgently needed, blue TADF emitters have not met stability requirement for applications. It is essential to elucidate the degradation mechanism and identify the tailored descriptor for material stability and device lifetime. Here, via in-material chemistry, we demonstrate chemical degradation of TADF materials involves critical role of bond cleavage at triplet state rather than singlet, and disclose the difference between bond dissociation energy of fragile bonds and first triplet state energy (BDE- E T1 ) is linearly correlated with logarithm of reported device lifetime for various blue TADF emitters. This significant quantitative correlation strongly reveals the degradation mechanism of TADF materials have general characteristic in essence and BDE- E T1 could be the shared “longevity gene”. Our findings provide a critical molecular descriptor for high-throughput-virtual-screening and rational design to unlock the full potential of TADF materials and devices. High throughput virtual screening of robust blue thermally activated delayed fluorescent emitters has yet been implemented. Here, authors reveal a linear relationship of the difference between bond dissociate energy and first triplet state energy with the logarithm of device operational lifetime.