Recent advances in hypervalent iodine(III)-catalyzed functionalization of alkenes

Hypervalent iodine(III) reagents have been well-developed and widely utilized in functionalization of alkenes, however, generally either stoichiometric amounts of iodine(III) reagents are required or stoichiometric oxidants such as CPBA are employed to in situ generate iodine(III) species. In this r...

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Published inBeilstein journal of organic chemistry Vol. 14; no. 1; pp. 1813 - 1825
Main Authors Li, Xiang, Chen, Pinhong, Liu, Guosheng
Format Journal Article
LanguageEnglish
Published Germany Beilstein-Institut zur Föerderung der Chemischen Wissenschaften 18.07.2018
Beilstein-Institut
Subjects
Acids
asymmetric catalysis
Chemistry
functionalization of alkenes
Hydrogen
hypervalent iodine(III)
Iodine
Ligands
Organic chemistry
Oxidants
Review
functionalization of alkenes
hypervalent iodine(III)
asymmetric catalysis
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Summary:Hypervalent iodine(III) reagents have been well-developed and widely utilized in functionalization of alkenes, however, generally either stoichiometric amounts of iodine(III) reagents are required or stoichiometric oxidants such as CPBA are employed to in situ generate iodine(III) species. In this review, recent developments of hypervalent iodine(III)-catalyzed functionalization of alkenes and asymmetric reactions using a chiral iodoarene are summarized.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-3
content type line 23
ObjectType-Review-1
ISSN:1860-5397
2195-951X
1860-5397
DOI:10.3762/bjoc.14.154