Qualitative and quantitative methods detection of SDS based on polyelectrolyte microcapsules

• Published in: Scientific reports Vol. 12; no. 1; pp. 232 - 7
• Main Authors: Kim, Aleksandr L., Musin, Egor V., Dubrovskii, Alexey V., Tikhonenko, Sergey A.
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 07.01.2022; Nature Publishing Group; Nature Portfolio
• Subjects: 631/158/2459; 631/158/858; 639/638/11; 639/638/169; 639/638/541; 704/172/169; Fluorescent indicators; Humanities and Social Sciences; Microcapsules; multidisciplinary; Pollutants; Polyallylamine; Science; Science (multidisciplinary); Sodium; Sodium lauryl sulfate; Sulfates; Surface water; Surfactants; Turbidimetry; Wastewater
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/s41598-021-04343-z

Sodium dodecyl sulfate (SDS) is the most widely used anionic surfactant. Its frequent use causes environmental pollution and negative effects on living organisms (even at low concentrations ≈ 20 μg/ml). Thus, cheap and fast methods are needed to detect this surfactant in wastewater and surface waters in order to prevent the negative effects of SDS on the environment and human beings. We discovered that sodium dodecyl sulfate is capable of destroying polyelectrolyte microcapsules, which has been demonstrated by the number of sedimented polyelectrolyte microcapsules (PMC) before and after incubation in SDS solution. Therefore, it was proposed to use PMCs to create qualitative and quantitative diagnostic systems for the determination of SDS in solution. The qualitative system is a polyelectrolyte microcapsules containing polyallylamine labeled with a fluorescent dye—FITC. An excess SDS concentration of more than 5 μg/ml in the analyzed medium leads to the destruction of PMC and an increase in the fluorescence intensity of the solution, which is recorded by a fluorometer. The quantitative diagnostic system is based on turbidimetry of the PMC suspension before and after incubation in an anionic surfactant solution. This system has a range of detectable SDS concentrations from 10 to 50 μg/ml, with a standard deviation of no more than 11%.