Mobilisation of deep crustal sulfide melts as a first order control on upper lithospheric metallogeny

• Published in: Nature communications Vol. 13; no. 1; p. 573
• Main Authors: Holwell, David A., Fiorentini, Marco L., Knott, Thomas R., McDonald, Iain, Blanks, Daryl E., Campbell McCuaig, T., Gorczyk, Weronika
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 31.01.2022; Nature Publishing Group; Nature Portfolio
• Subjects: 140/125; 147/135; 704/2151/213/4115; 704/2151/431; Copper; Earth mantle; Fluxing; Fractionation; Gold; Heavy metals; Humanities and Social Sciences; Lithosphere; Magma; Metals; Mineral deposits; multidisciplinary; Olivine; Porphyry copper; Science; Science (multidisciplinary); Solid phases; Sulfide; Sulfides; Terrestrial environments; Volatile compounds; Volatiles
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/s41467-022-28275-y

Magmatic arcs are terrestrial environments where lithospheric cycling and recycling of metals and volatiles is enhanced. However, the first-order mechanism permitting the episodic fluxing of these elements from the mantle through to the outer Earth’s spheres has been elusive. To address this knowledge gap, we focus on the textural and minero-chemical characteristics of metal-rich magmatic sulfides hosted in amphibole-olivine-pyroxene cumulates in the lowermost crust. We show that in cumulates that were subject to increasing temperature due to prolonged mafic magmatism, which only occurs episodically during the complex evolution of any magmatic arc, Cu-Au-rich sulfide can exist as liquid while Ni-Fe rich sulfide occurs as a solid phase. This scenario occurs within a ‘Goldilocks’ temperature zone at ~1100–1200 °C, typical of the base of the crust in arcs, which permits episodic fractionation and mobilisation of Cu-Au-rich sulfide liquid into permeable melt networks that may ascend through the lithosphere providing metals for porphyry and epithermal ore deposits. The presence and mobility of metal-rich sulfides in lower crustal magma chambers can act as a gateway for metals to be trapped, or released into ascending magmas that are then able to form upper crustal porphyry copper and gold deposits.