Realization of p-type gallium nitride by magnesium ion implantation for vertical power devices

• Published in: Scientific reports Vol. 9; no. 1; pp. 8796 - 9
• Main Authors: Shi, Ya-Ting, Ren, Fang-Fang, Xu, Wei-Zong, Chen, Xuanhu, Ye, Jiandong, Li, Li, Zhou, Dong, Zhang, Rong, Zheng, Youdou, Tan, Hark Hoe, Jagadish, Chennupati, Lu, Hai
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 19.06.2019; Nature Publishing Group
• Subjects: 639/166/987; 639/301/1005; Conduction; Gallium; Humanities and Social Sciences; Ion implantation; Magnesium; multidisciplinary; Science; Science (multidisciplinary); Voltage
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/s41598-019-45177-0

Implementing selective-area p-type doping through ion implantation is the most attractive choice for the fabrication of GaN-based bipolar power and related devices. However, the low activation efficiency of magnesium (Mg) ions and the inevitable surface decomposition during high-temperature activation annealing process still limit the use of this technology for GaN-based devices. In this work, we demonstrate successful p-type doping of GaN using protective coatings during a Mg ion implantation and thermal activation process. The p-type conduction of GaN is evidenced by the positive Seebeck coefficient obtained during thermopower characterization. On this basis, a GaN p-i-n diode is fabricated, exhibiting distinct rectifying characteristics with a turn-on voltage of 3 V with an acceptable reverse breakdown voltage of 300 V. Electron beam induced current (EBIC) and electroluminescent (EL) results further confirm the formation of p-type region due to Mg ion implantation and subsequent thermal activation. This repeatable and uniform manufacturing process can be implemented in mass production of GaN devices for versatile power and optoelectronic applications.