Catalytic enantioselective C(sp3)–H functionalization involving radical intermediates
Recently, with the boosted development of radical chemistry, enantioselective functionalization of C( sp 3 )–H bonds via a radical pathway has witnessed a renaissance. In principle, two distinct catalytic modes, distinguished by the steps in which the stereochemistry is determined (the radical forma...
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| Published in | Nature communications Vol. 12; no. 1; pp. 475 - 9 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
London
Nature Publishing Group UK
20.01.2021
Nature Publishing Group Nature Portfolio |
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| Abstract | Recently, with the boosted development of radical chemistry, enantioselective functionalization of C(
sp
3
)–H bonds via a radical pathway has witnessed a renaissance. In principle, two distinct catalytic modes, distinguished by the steps in which the stereochemistry is determined (the radical formation step or the radical functionalization step), can be devised. This Perspective discusses the state-of-the-art in the area of catalytic enantioselective C(
sp
3
)–H functionalization involving radical intermediates as well as future challenges and opportunities.
Enantioselective functionalization of ubiquitous C(sp
3
)–H bonds via radical species has witnessed a renaissance in the past years. Here, the authors summarize the main achievements in the field by identifying two main reaction pathways determining the stereochemistry and give an outlook on future challenges and opportunities. |
|---|---|
| AbstractList | Enantioselective functionalization of ubiquitous C(sp3)–H bonds via radical species has witnessed a renaissance in the past years. Here, the authors summarize the main achievements in the field by identifying two main reaction pathways determining the stereochemistry and give an outlook on future challenges and opportunities. Recently, with the boosted development of radical chemistry, enantioselective functionalization of C(sp )-H bonds via a radical pathway has witnessed a renaissance. In principle, two distinct catalytic modes, distinguished by the steps in which the stereochemistry is determined (the radical formation step or the radical functionalization step), can be devised. This Perspective discusses the state-of-the-art in the area of catalytic enantioselective C(sp )-H functionalization involving radical intermediates as well as future challenges and opportunities. Recently, with the boosted development of radical chemistry, enantioselective functionalization of C(sp3)–H bonds via a radical pathway has witnessed a renaissance. In principle, two distinct catalytic modes, distinguished by the steps in which the stereochemistry is determined (the radical formation step or the radical functionalization step), can be devised. This Perspective discusses the state-of-the-art in the area of catalytic enantioselective C(sp3)–H functionalization involving radical intermediates as well as future challenges and opportunities.Enantioselective functionalization of ubiquitous C(sp3)–H bonds via radical species has witnessed a renaissance in the past years. Here, the authors summarize the main achievements in the field by identifying two main reaction pathways determining the stereochemistry and give an outlook on future challenges and opportunities. Recently, with the boosted development of radical chemistry, enantioselective functionalization of C(sp3)-H bonds via a radical pathway has witnessed a renaissance. In principle, two distinct catalytic modes, distinguished by the steps in which the stereochemistry is determined (the radical formation step or the radical functionalization step), can be devised. This Perspective discusses the state-of-the-art in the area of catalytic enantioselective C(sp3)-H functionalization involving radical intermediates as well as future challenges and opportunities.Recently, with the boosted development of radical chemistry, enantioselective functionalization of C(sp3)-H bonds via a radical pathway has witnessed a renaissance. In principle, two distinct catalytic modes, distinguished by the steps in which the stereochemistry is determined (the radical formation step or the radical functionalization step), can be devised. This Perspective discusses the state-of-the-art in the area of catalytic enantioselective C(sp3)-H functionalization involving radical intermediates as well as future challenges and opportunities. Recently, with the boosted development of radical chemistry, enantioselective functionalization of C( sp 3 )–H bonds via a radical pathway has witnessed a renaissance. In principle, two distinct catalytic modes, distinguished by the steps in which the stereochemistry is determined (the radical formation step or the radical functionalization step), can be devised. This Perspective discusses the state-of-the-art in the area of catalytic enantioselective C( sp 3 )–H functionalization involving radical intermediates as well as future challenges and opportunities. Recently, with the boosted development of radical chemistry, enantioselective functionalization of C( sp 3 )–H bonds via a radical pathway has witnessed a renaissance. In principle, two distinct catalytic modes, distinguished by the steps in which the stereochemistry is determined (the radical formation step or the radical functionalization step), can be devised. This Perspective discusses the state-of-the-art in the area of catalytic enantioselective C( sp 3 )–H functionalization involving radical intermediates as well as future challenges and opportunities. Enantioselective functionalization of ubiquitous C(sp 3 )–H bonds via radical species has witnessed a renaissance in the past years. Here, the authors summarize the main achievements in the field by identifying two main reaction pathways determining the stereochemistry and give an outlook on future challenges and opportunities. |
| ArticleNumber | 475 |
| Author | Gu, Qiang-Shuai Liu, Xin-Yuan Zhang, Chi Li, Zhong-Liang |
| Author_xml | – sequence: 1 givenname: Chi surname: Zhang fullname: Zhang, Chi organization: Shenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology – sequence: 2 givenname: Zhong-Liang surname: Li fullname: Li, Zhong-Liang organization: Academy for Advanced Interdisciplinary Studies and Department of Chemistry, Southern University of Science and Technology – sequence: 3 givenname: Qiang-Shuai orcidid: 0000-0002-3840-425X surname: Gu fullname: Gu, Qiang-Shuai email: guqs@sustech.edu.cn organization: Academy for Advanced Interdisciplinary Studies and Department of Chemistry, Southern University of Science and Technology – sequence: 4 givenname: Xin-Yuan orcidid: 0000-0002-6978-6465 surname: Liu fullname: Liu, Xin-Yuan email: liuxy3@sustech.edu.cn organization: Shenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/33473126$$D View this record in MEDLINE/PubMed |
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| Snippet | Recently, with the boosted development of radical chemistry, enantioselective functionalization of C(
sp
3
)–H bonds via a radical pathway has witnessed a... Recently, with the boosted development of radical chemistry, enantioselective functionalization of C(sp )-H bonds via a radical pathway has witnessed a... Recently, with the boosted development of radical chemistry, enantioselective functionalization of C(sp3)–H bonds via a radical pathway has witnessed a... Recently, with the boosted development of radical chemistry, enantioselective functionalization of C(sp3)-H bonds via a radical pathway has witnessed a... Enantioselective functionalization of ubiquitous C(sp3)–H bonds via radical species has witnessed a renaissance in the past years. Here, the authors summarize... |
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| SubjectTerms | 639/638/403/933 639/638/403/935 639/638/77/883 Acids Alcohol Chemistry Enantiomers Humanities and Social Sciences Intermediates multidisciplinary Oxidation Perspective Science Science (multidisciplinary) Stereochemistry |
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| Title | Catalytic enantioselective C(sp3)–H functionalization involving radical intermediates |
| URI | https://link.springer.com/article/10.1038/s41467-020-20770-4 https://www.ncbi.nlm.nih.gov/pubmed/33473126 https://www.proquest.com/docview/2479188097 https://www.proquest.com/docview/2479728266 https://pubmed.ncbi.nlm.nih.gov/PMC7817665 https://doaj.org/article/f28f20eec4be4ea6b4db528d8daffcbb |
| Volume | 12 |
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