Hyperfine‐Interaction‐Driven Suppression of Quantum Tunneling at Zero Field in a Holmium(III) Single‐Ion Magnet
An extremely rare non‐Kramers holmium(III) single‐ion magnet (SIM) is reported to be stabilized in the pentagonal‐bipyramidal geometry by a phosphine oxide with a high energy barrier of 237(4) cm−1. The suppression of the quantum tunneling of magnetization (QTM) at zero field and the hyperfine struc...
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| Published in | Angewandte Chemie International Edition Vol. 56; no. 18; pp. 4996 - 5000 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
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Germany
Wiley Subscription Services, Inc
24.04.2017
Wiley-VCH Verlag |
| Edition | International ed. in English |
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| Abstract | An extremely rare non‐Kramers holmium(III) single‐ion magnet (SIM) is reported to be stabilized in the pentagonal‐bipyramidal geometry by a phosphine oxide with a high energy barrier of 237(4) cm−1. The suppression of the quantum tunneling of magnetization (QTM) at zero field and the hyperfine structures originating from field‐induced QTMs can be observed even from the field‐dependent alternating‐current magnetic susceptibility in addition to single‐crystal hysteresis loops. These dramatic dynamics were attributed to the combination of the favorable crystal‐field environment and the hyperfine interactions arising from 165Ho (I=7/2) with a natural abundance of 100 %.
An extremely rare non‐Kramers holmium(III) single‐ion magnet is reported. The suppression of the quantum tunneling of magnetization at zero field and the hyperfine structures were observed in AC magnetic susceptibility measurements, and were attributed to the combination of a favorable crystal‐field environment and the hyperfine interactions arising from 165Ho (I=7/2) with a natural abundance of 100 %. |
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| AbstractList | An extremely rare non‐Kramers holmium(III) single‐ion magnet (SIM) is reported to be stabilized in the pentagonal‐bipyramidal geometry by a phosphine oxide with a high energy barrier of 237(4) cm−1. The suppression of the quantum tunneling of magnetization (QTM) at zero field and the hyperfine structures originating from field‐induced QTMs can be observed even from the field‐dependent alternating‐current magnetic susceptibility in addition to single‐crystal hysteresis loops. These dramatic dynamics were attributed to the combination of the favorable crystal‐field environment and the hyperfine interactions arising from 165Ho (I=7/2) with a natural abundance of 100 %.
An extremely rare non‐Kramers holmium(III) single‐ion magnet is reported. The suppression of the quantum tunneling of magnetization at zero field and the hyperfine structures were observed in AC magnetic susceptibility measurements, and were attributed to the combination of a favorable crystal‐field environment and the hyperfine interactions arising from 165Ho (I=7/2) with a natural abundance of 100 %. An extremely rare non-Kramers holmium(III) single-ion magnet (SIM) is reported to be stabilized in the pentagonal-bipyramidal geometry by a phosphine oxide with a high energy barrier of 237(4) cm . The suppression of the quantum tunneling of magnetization (QTM) at zero field and the hyperfine structures originating from field-induced QTMs can be observed even from the field-dependent alternating-current magnetic susceptibility in addition to single-crystal hysteresis loops. These dramatic dynamics were attributed to the combination of the favorable crystal-field environment and the hyperfine interactions arising from Ho (I=7/2) with a natural abundance of 100 %. An extremely rare non‐Kramers holmium(III) single‐ion magnet (SIM) is reported to be stabilized in the pentagonal‐bipyramidal geometry by a phosphine oxide with a high energy barrier of 237(4) cm −1 . The suppression of the quantum tunneling of magnetization (QTM) at zero field and the hyperfine structures originating from field‐induced QTMs can be observed even from the field‐dependent alternating‐current magnetic susceptibility in addition to single‐crystal hysteresis loops. These dramatic dynamics were attributed to the combination of the favorable crystal‐field environment and the hyperfine interactions arising from 165 Ho ( I =7/2) with a natural abundance of 100 %. An extremely rare non-Kramers holmium(III) single-ion magnet (SIM) is reported to be stabilized in the pentagonal-bipyramidal geometry by a phosphine oxide with a high energy barrier of 237(4)cm-1. The suppression of the quantum tunneling of magnetization (QTM) at zero field and the hyperfine structures originating from field-induced QTMs can be observed even from the field-dependent alternating-current magnetic susceptibility in addition to single-crystal hysteresis loops. These dramatic dynamics were attributed to the combination of the favorable crystal-field environment and the hyperfine interactions arising from 165Ho (I=7/2) with a natural abundance of 100%. An extremely rare non-Kramers holmium(III) single-ion magnet (SIM) is reported to be stabilized in the pentagonal-bipyramidal geometry by a phosphine oxide with a high energy barrier of 237(4) cm-1 . The suppression of the quantum tunneling of magnetization (QTM) at zero field and the hyperfine structures originating from field-induced QTMs can be observed even from the field-dependent alternating-current magnetic susceptibility in addition to single-crystal hysteresis loops. These dramatic dynamics were attributed to the combination of the favorable crystal-field environment and the hyperfine interactions arising from 165 Ho (I=7/2) with a natural abundance of 100 %. |
| Author | Liu, Jun‐Liang Wernsdorfer, Wolfgang Tong, Ming‐Liang Chen, Yan‐Cong Chen, Xiao‐Ming Chibotaru, Liviu F. Liu, Dan |
| Author_xml | – sequence: 1 givenname: Yan‐Cong surname: Chen fullname: Chen, Yan‐Cong organization: Sun Yat-Sen University – sequence: 2 givenname: Jun‐Liang orcidid: 0000-0002-5811-6300 surname: Liu fullname: Liu, Jun‐Liang email: liujliang5@mail.sysu.edu.cn organization: Sun Yat-Sen University – sequence: 3 givenname: Wolfgang surname: Wernsdorfer fullname: Wernsdorfer, Wolfgang organization: Karlsruhe Institute of Technology – sequence: 4 givenname: Dan surname: Liu fullname: Liu, Dan organization: Katholieke Universiteit Leuven – sequence: 5 givenname: Liviu F. surname: Chibotaru fullname: Chibotaru, Liviu F. organization: Katholieke Universiteit Leuven – sequence: 6 givenname: Xiao‐Ming surname: Chen fullname: Chen, Xiao‐Ming organization: Sun Yat-Sen University – sequence: 7 givenname: Ming‐Liang orcidid: 0000-0003-4725-0798 surname: Tong fullname: Tong, Ming‐Liang email: tongml@mail.sysu.edu.cn organization: Sun Yat-Sen University |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/28295930$$D View this record in MEDLINE/PubMed https://hal.science/hal-01978462$$DView record in HAL |
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| Keywords | magnetic properties hyperfine interactions holmium single-molecule magnets lanthanides |
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| Snippet | An extremely rare non‐Kramers holmium(III) single‐ion magnet (SIM) is reported to be stabilized in the pentagonal‐bipyramidal geometry by a phosphine oxide... An extremely rare non-Kramers holmium(III) single-ion magnet (SIM) is reported to be stabilized in the pentagonal-bipyramidal geometry by a phosphine oxide... |
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| SubjectTerms | Abundance Chemical Sciences Energy Holmium hyperfine interactions Hysteresis Hysteresis loops lanthanides Magnetic permeability magnetic properties Magnetic susceptibility Magnetization Phosphine Phosphine oxide Quantum tunnelling Single crystals single-molecule magnets |
| Title | Hyperfine‐Interaction‐Driven Suppression of Quantum Tunneling at Zero Field in a Holmium(III) Single‐Ion Magnet |
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