Significance of crystallochemical factors in chemical reactions into the structure of solids

The chemical reaction of the formation of compounds within the structure of solid as a reaction medium—internal reactions—is the subject of the article. The mechanism of these reactions on the example silicate mineral structure and nanocrystallization of oxide glasses is considered. Local atoms inte...

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Bibliographic Details
Published inJournal of thermal analysis and calorimetry Vol. 109; no. 2; pp. 763 - 766
Main Authors Stoch, Leszek, Stoch, Paweł
Format Journal Article
LanguageEnglish
Published Dordrecht Springer Netherlands 01.08.2012
Springer
Subjects
Analytical Chemistry
Applied sciences
Building materials. Ceramics. Glasses
Chemical industry and chemicals
Chemical properties
Chemistry
Chemistry and Materials Science
Exact sciences and technology
Glass-ceramics
Glasses
Inorganic Chemistry
Measurement Science and Instrumentation
Miscellaneous
Physical Chemistry
Polymer Sciences
Silicate minerals
Silicates
Solid state reactions
Glass nanocrystallization
Electronegativity
Clay
Crystallization
Glass
Silicates
Dehydroxylation
Inorganic anion
Chemical reaction
Solid state reaction
Kaolinite
Glass ceramics
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Summary:The chemical reaction of the formation of compounds within the structure of solid as a reaction medium—internal reactions—is the subject of the article. The mechanism of these reactions on the example silicate mineral structure and nanocrystallization of oxide glasses is considered. Local atoms interaction analysis based on the electronegativity of and ionicity of the chemical bonds values helps to understand this mechanism and predict course of intrastructural thermal processes.
ISSN:1388-6150
1572-8943
DOI:10.1007/s10973-012-2203-z