Biorenewable triblock copolymers consisting of l-lactide and ε-caprolactone for removing organic pollutants from water: a lifecycle neutral solution

• Published in: BMC chemistry Vol. 13; no. 1; pp. 122 - 13
• Main Authors: Bernhardt, Katrina T., Collins, Haley G., Balija, Amy M.
• Format: Journal Article
• Language: English
• Published: Cham Springer International Publishing 22.10.2019; Springer Nature B.V; BMC
• Subjects: Adsorption; Aqueous environments; Aqueous solutions; Biorenewable polymers; Block copolymers; Chemistry; Chemistry and Materials Science; Chemistry/Food Science; Copolymers; Dichloromethane; Materials and Macromolecular Chemistry; Phenanthrene; Pollutants; Pollution remediation; Poly(lactic acid); Poly(ε-caprolactone); Polycyclic aromatic hydrocarbons; Polymers; Research Article; Rose Bengal; Selectivity; System effectiveness; Water pollution; Pollution remediation; Poly(ε-caprolactone); Poly(lactic acid); Polycyclic aromatic hydrocarbons; Biorenewable polymers; Rose Bengal
• ISSN: 2661-801X; 2661-801X
• DOI: 10.1186/s13065-019-0638-z

Background Current methods of removing organic pollutants from water are becoming ineffective as the world population increases. In this study, a series of biorenewable triblock copolymers with hydrophobic poly(ε-caprolactone) block and hydrophilic poly( l -lactide) blocks were synthesized and tested as agents to remove environmental pollutants from an aqueous solution. The percent of pollutant removed and equilibrium inclusion constants were calculated for the polymers. These values were compared to previously known removal agents for their effectiveness. Results Triblock copolymer samples removed over 70% of the polycyclic aromatic hydrocarbon (PAH) phenanthrene from an aqueous solution, with selectivity for the adsorption of phenanthrene over other PAHs tested. The inclusion constant was 7.4 × 10 5  M −1 and adsorption capacity was 5.8 × 10 −7 mol phenanthrene/g polymer. Rose Bengal was used to further probe the nature of interactions between the copolymers and a small molecule guest. Solid samples of the block -poly( l -lactide)– block -poly(ε-caprolactone)– block -poly( l -lactide) (PLLA–PCL–PLLA) systems were found to rapidly remove over 90% of Rose Bengal from aqueous solution, resulting in a complete disappearance of the characteristic pink color. Solutions of the copolymers in dichloromethane also removed Rose Bengal from water with a similar level of efficiency. Large inclusion constant values were obtained, ranging from 1.0 × 10 5 to 7.9 × 10 5  M −1 , and the average adsorption capacity value of 6.2 × 10 −7  mol/g polymer was determined. Aged polymer samples exhibited different adsorption characteristics and mechanistic theories for the removal of Rose Bengal were determined. Conclusion The triblock copolymer consisting of l -lactide and ε-caprolactone was effective in removing various organic pollutants in aqueous environments. It is a biorenewable material which leads to minimal waste production during its lifecycle. These polymers were in general more effective in removing organic pollutants than commercially available pollution removal systems.