Transparent Bendable Secondary Zinc-Air Batteries by Controlled Void Ionic Separators

• Published in: Scientific reports Vol. 9; no. 1; p. 3175
• Main Authors: Kwon, Ohchan, Hwang, Ho Jung, Ji, Yunseong, Jeon, Ok Sung, Kim, Jeong Pil, Lee, Chanmin, Shul, Yong Gun
• Format: Journal Article
• Language: English
• Published: England Nature Publishing Group 28.02.2019; Nature Publishing Group UK
• Subjects: Electrical conductivity; Electrodes; Electrolytes; Optical properties; Separators
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/s41598-019-38552-4

First ever transparent bendable secondary zinc-air batteries were fabricated. Transparent stainless-steel mesh was utilized as the current collector for the electrodes due to its reliable mechanical stability and electrical conductivity. After which separate methods were used to apply the active redox species. For the preparation of the anode, zinc was loaded by an electroplating process to the mesh. For the cathode, catalyst ink solution was spray coated with an airbrush for desired dimensions. An alkaline gel electrolyte layer was used for the electrolyte. Microscale domain control of the materials becomes a crucial factor for fabricating transparent batteries. As for the presented cell, anionic exchange polymer layer has been uniquely incorporated on to the cathode mesh as the separator which becomes a key procedure in the fabrication process for obtaining the desired optical properties of the battery. The ionic resin is applied in a fashion where controlled voids exist between the openings of the grid which facilitates light passage while guaranteeing electrical insulation between the electrodes. Further analysis correlates the electrode dimensions to the transparency of the system. Recorded average light transmittance is 48.8% in the visible light region and exhibited a maximum power density of 9.77 mW/cm . The produced battery shows both transparent and flexible properties while maintaining a stable discharge/charge operation.