Formate‐Mediated Cross‐Electrophile Reductive Coupling of Aryl Iodides and Bromopyridines

Two catalytic systems for the formate‐mediated cross‐electrophile reductive coupling of aryl iodides with 6‐bromopyridines are described. Using homogenous rhodium or heterogeneous palladium catalysts, the products of reductive biaryl cross‐coupling could be formed in moderate yield with excellent le...

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Bibliographic Details
Published inIsrael journal of chemistry Vol. 61; no. 5-6; pp. 298 - 301
Main Authors Schwartz, Leyah A., Spielmann, Kim, Swyka, Robert A., Xiang, Ming, Krische, Michael J.
Format Journal Article
LanguageEnglish
Published Germany Wiley Subscription Services, Inc 01.05.2021
Subjects
Aromatic compounds
Cross coupling
cross-electrophile coupling
formate
Iodides
Palladium
reductive coupling
Rhodium
formate
palladium
cross-electrophile coupling
reductive coupling
rhodium
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Summary:Two catalytic systems for the formate‐mediated cross‐electrophile reductive coupling of aryl iodides with 6‐bromopyridines are described. Using homogenous rhodium or heterogeneous palladium catalysts, the products of reductive biaryl cross‐coupling could be formed in moderate yield with excellent levels of chemoselectivity.
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Dedicated to Professor Barry M. Trost on the occasion of his 80
birthday.
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Dedicated to Professor Barry M. Trost on the occasion of his 80th birthday.
ISSN:0021-2148
1869-5868
DOI:10.1002/ijch.202000069