Treatment of sugarcane vinasse by combination of coagulation/flocculation and Fenton’s oxidation

• Published in: Journal of environmental management Vol. 181; pp. 237 - 248
• Main Authors: Guerreiro, Lígia F., Rodrigues, Carmen S.D., Duda, Rose M., de Oliveira, Roberto A., Boaventura, Rui A.R., Madeira, Luis M.
• Format: Journal Article
• Language: English
• Published: England Elsevier Ltd 01.10.2016; Academic Press Ltd
• Subjects: Anaerobic effluent biodegradability; Biodegradation, Environmental; Biological Oxygen Demand Analysis; Chemical oxygen demand; Coagulation; Coagulation/flocculation; Economic analysis; Fenton’s reaction; Flocculation; Hydrogen peroxide; Hydrogen Peroxide - chemistry; Hydrogen-Ion Concentration; Industrial Waste; Iron - chemistry; Oxidation; Oxidation-Reduction; Saccharum - chemistry; Sugarcane; Sugarcane vinasse; Temperature; Toxicity; Vibrio fischeri; Waste Disposal, Fluid - methods; Waste Water - chemistry; Economic analysis; Anaerobic effluent biodegradability; Coagulation/flocculation; Sugarcane vinasse; Fenton’s reaction; Toxicity
• ISSN: 0301-4797; 1095-8630
• DOI: 10.1016/j.jenvman.2016.06.027

The efficiency of individual and integrated processes applied to organic matter reduction and biodegradability improvement of a biodigested sugarcane vinasse wastewater was assessed. Strategies considered were Fenton’s oxidation (Strategy 1), coagulation/flocculation (Strategy 2) and the combination of both processes (coagulation/flocculation followed by Fenton’s reaction) – Strategy 3. It was found that Fenton’s oxidation per se allowed reducing the organic matter, increasing the wastewater biodegradability and a non-toxic effluent was generated; however the cost of treatment was very high (86.6 R$/m3 – 21.2 €/m3). Under optimized conditions, coagulation/flocculation provided a slight increase in effluent’s biodegradability, toxicity towards Vibrio fischeri was also eliminated and moderate removals of total organic carbon – TOC – (30.5%), biological oxygen demand – BOD5 – (27.9%) and chemical oxygen demand – COD – (43.6%) were achieved; however, the operating costs are much smaller. The use of dissolved iron resulting from coagulation/flocculation (270 mg/L) as catalyst in the second stage – Fenton’s oxidation – was shown to be an innovative and economically attractive strategy. Under optimal conditions overall removals of 51.6% for TOC, 45.7% for BOD5 and 69.2% for COD were achieved, and a biodegradable (BOD5:COD ratio = 0.54) and non-toxic effluent was obtained. In order to increase the efficiency of the process but using less hydrogen peroxide, the Fenton’s oxidation was performed by gradually adding the oxidant. This procedure allowed to obtain the highest organic matter removal efficiency (as compared with the addition of all hydrogen peroxide at the beginning of the reaction). This way it was possible to minimize the reagent consumption and, consequently, reduce the treatment cost. [Display omitted] •Different strategies are compared for treating sugarcane vinasse wastewater.•Dissolved Fe from coagulation can be used as catalyst in Fenton’s reaction.•Coagulation/flocculation plus Fenton oxidation presents lower operating costs.•Integrated process allows reaching better performances and a non-toxic effluent.