Synthesis of Indenones via Persulfate Promoted Radical Alkylation/Cyclization of Biaryl Ynones with 1,4-Dihydropyridines

The oxidative radical cascade cyclization of alkynes has emerged as a versatile strategy for the efficient construction of diverse structural units and complex molecules in organic chemistry. This work reports an alkyl radical initiated 5- -trig cyclization of biaryl ynones with 1,4-dihydropyridines...

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Published inMolecules (Basel, Switzerland) Vol. 29; no. 2; p. 458
Main Authors Wang, Wanwan, Yu, Lei
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 01.01.2024
MDPI
Subjects
alkylation
biaryl ynones
Chromatography
cyclization
indenones
radical
Solvents
China
indenones
alkylation
biaryl ynones
radical
cyclization
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Summary:The oxidative radical cascade cyclization of alkynes has emerged as a versatile strategy for the efficient construction of diverse structural units and complex molecules in organic chemistry. This work reports an alkyl radical initiated 5- -trig cyclization of biaryl ynones with 1,4-dihydropyridines to selectively synthesize indenones.
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ISSN:1420-3049
1420-3049
DOI:10.3390/molecules29020458