Influence of amine and vinyl functional groups of silanes on total performance of thermoplastic-based composites

• Published in: Construction & building materials Vol. 172; pp. 98 - 105
• Main Authors: Koohestani, Babak, Khodadadi Darban, Ahmad, Yilmaz, Erol, Mokhtari, Pozhhan, Ganetri, Ikram
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 30.05.2018; Elsevier B.V
• Subjects: Amine; Analysis; Composite building materials; High density polyethylene; Mechanical properties; Mineral fillers; Organosilane; Thermal properties; Treatment; Vinyl; Iran; Morocco; Turkey; Organosilane; Amine; Vinyl; Treatment; Mineral fillers; High density polyethylene
• ISSN: 0950-0618; 1879-0526
• DOI: 10.1016/j.conbuildmat.2018.03.235

•Silane treated mineral fillers improved the total performance of neat HDPE and WPC.•The electrostatic forces were responsible for the affinity between filler and matrix.•Amine functional groups considerably broadened the elongation of HDPE at break.•The affinity of Vinyl group and HDPE resulted in the agglomeration of mineral fillers.•No covalent bonding was occurred between organofunctional groups of silane and HDPE. The influence of amine (polar) and vinyl (nonpolar) functionalized organosilanes were investigated on the total performance of neat high-density polyethylene (HDPE) and wood-HDPE composites. Thus, micro-size silicate-based mineral fillers were treated with 3 mass% amine and vinyl silanes and then 15 and 30 mass% plus 1 and 5 mass% of treated mineral fillers were blended with neat HDPE and wood-HDPE composites, respectively. Based on the achieved mechanical, thermal, rheological, water absorption, and microstructural results, the affinity of amine functional group and HDPE matrix predominantly decreased the rigidity, improved the thermal stability, reduced the water uptake, and facilitated the dispersion of fillers within the polymeric composite. As demonstrated by FTIR test, due to the lack of chemical bonding between the polyethylene and amine/vinyl functional groups, the electrostatic forces can explain the affinity between the filler and matrix. The affinity of the non-polar vinyl group and non-polar HDPE matrix resulted in the agglomeration of mineral fillers that can represent the repulsive electrostatic forces between the vinyl treated filler and the polymeric matrix.