Detection of OH radicals as the effect of Pt particles in the membrane of polymer electrolyte fuel cells
The formation of OH radicals ( OH) for polymer electrolyte fuel cell (PEFC) was investigated with a homemade test cell by means of a fluorescence probe method for several kinds of membrane electrode assembly (MEA) consisting of Nafion. After 12-h operation under open circuit condition, OH was detect...
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Published in | Journal of power sources Vol. 195; no. 15; pp. 4647 - 4652 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Amsterdam
Elsevier B.V
01.08.2010
Elsevier |
Subjects | |
Online Access | Get full text |
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Summary: | The formation of OH radicals (
OH) for polymer electrolyte fuel cell (PEFC) was investigated with a homemade test cell by means of a fluorescence probe method for several kinds of membrane electrode assembly (MEA) consisting of Nafion. After 12-h operation under open circuit condition,
OH was detected at both the anode and the cathode sides but the amount was much larger for the anode side. The formation of
OH considerably depended on the amount of Pt/C catalyst loaded in the MEA. Dispersion of Pt particles in Nafion membranes increased the
OH formation, but Pt ions did not. Based on the results, the formation mechanism was discussed. |
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Bibliography: | ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
ISSN: | 0378-7753 1873-2755 |
DOI: | 10.1016/j.jpowsour.2010.02.010 |