Calorimetric studies of Cu–Li, Li–Sn, and Cu–Li–Sn

• Published in: The Journal of chemical thermodynamics Vol. 61; no. 100; pp. 105 - 116
• Main Authors: Fürtauer, S., Tserenjav, E., Yakymovych, A., Flandorfer, H.
• Format: Journal Article
• Language: English
• Published: England Elsevier Ltd 01.06.2013; Academic Press
• Subjects: Calorimetry; Copper; Cu–Li; Cu–Li–Sn; Drop calorimetry; Endothermic reactions; Enthalpy; Extrapolation; Integrals; Li–Sn; Mathematical models; Molar mixing enthalpy; Temperature dependence; Molar mixing enthalpy; Cu–Li; Drop calorimetry; Li–Sn; Cu–Li–Sn
• ISSN: 0021-9614; 1096-3626
• DOI: 10.1016/j.jct.2013.01.030

► Li–Sn at 773K and 1073K. ► Cu–Li at 1073K. ► Cu–Li–Sn at 1073K (1st publication). Integral molar enthalpies of mixing were determined by drop calorimetry for Cu–Li–Sn at 1073K along five sections xCu/xSn≈1:1, xCu/xSn≈2:3, xCu/xSn≈1:4, xLi/xSn≈1:1, and xLi/xSn≈1:4. The integral and partial molar mixing enthalpies of Cu–Li and Li–Sn were measured at the same temperature, for Li–Sn in addition at 773K. All binary data could be described by Redlich–Kister-polynomials. Cu–Li shows an endothermic mixing effect with a maximum in the integral molar mixing enthalpy of ∼5300J·mol−1 at xCu=0.5, Li–Sn an exothermic minimum of ∼ −37,000J·mol−1 at xSn∼0.2. For Li–Sn no significant temperature dependence between 773K and 1073K could be deduced. Our measured ternary data were fitted on the basis of an extended Redlich–Kister–Muggianu model for substitutional solutions. Additionally, a comparison of these results to the extrapolation model of Chou is given.