Adsorption of methylene blue onto bamboo-based activated carbon: Kinetics and equilibrium studies

• Published in: Journal of hazardous materials Vol. 141; no. 3; pp. 819 - 825
• Main Authors: Hameed, B.H., Din, A.T.M., Ahmad, A.L.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 22.03.2007; Elsevier
• Subjects: Activated carbon; Adsorption; Applied sciences; Bamboo; Bambusa; Carbon - chemistry; Chemical engineering; Coloring Agents - chemistry; Coloring Agents - isolation & purification; Exact sciences and technology; Isotherm; Kinetics; Methylene blue; Methylene Blue - chemistry; Methylene Blue - isolation & purification; Pollution; Waste Disposal, Fluid - methods; Water Pollutants, Chemical - chemistry; Water Pollutants, Chemical - isolation & purification; Water Purification - methods; Isotherm; Kinetics; Bamboo; Activated carbon; Methylene blue; Second order; Dyes; Carbon dioxide; Adsorption isotherm; Adsorption capacity; Activation; Modeling; Kinetic model; Adsorption; First order; Kinetic parameter
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2006.07.049

Bamboo, an abundant and inexpensive natural resource in Malaysia was used to prepare activated carbon by physiochemical activation with potassium hydroxide (KOH) and carbon dioxide (CO 2) as the activating agents at 850 °C for 2 h. The adsorption equilibrium and kinetics of methylene blue dye on such carbon were then examined at 30 °C. Adsorption isotherm of the methylene blue (MB) on the activated carbon was determined and correlated with common isotherm equations. The equilibrium data for methylene blue adsorption well fitted to the Langmuir equation, with maximum monolayer adsorption capacity of 454.2 mg/g. Two simplified kinetic models including pseudo-first-order and pseudo-second-order equation were selected to follow the adsorption processes. The adsorption of methylene blue could be best described by the pseudo-second-order equation. The kinetic parameters of this best-fit model were calculated and discussed.