OO Bond Formation Mediated by a Hexanuclear Iron Complex Supported on a Stannoxane Core

The FeII complex of a hexanuclear non‐heme ligand performs an OO bond formation reaction using iodosobenzene as the oxygen source. On the basis of infrared, UV/Vis, kinetic and DFT studies a radical coupled OO bond formation mechanism is proposed (see scheme). These findings are extremely importan...

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Published inChemistry : a European journal Vol. 18; no. 10; pp. 2787 - 2791
Main Authors Kundu, Subrata, Matito, Eduard, Walleck, Stephan, Pfaff, Florian F., Heims, Florian, Rábay, Battist, Luis, Josep M., Company, Anna, Braun, Beatrice, Glaser, Thorsten, Ray, Kallol
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 05.03.2012
WILEY‐VCH Verlag
Subjects
Bonding
Catalysis
Infrared
Iron
Iron and steel industry
iron-oxo intermediates
Joining
Ligands
OO bond formation
polynuclear ligands
porphyrinoids
Radicals
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Summary:The FeII complex of a hexanuclear non‐heme ligand performs an OO bond formation reaction using iodosobenzene as the oxygen source. On the basis of infrared, UV/Vis, kinetic and DFT studies a radical coupled OO bond formation mechanism is proposed (see scheme). These findings are extremely important for the design and discovery of faster and cheaper water oxidation catalysts.
Bibliography:MEC
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ArticleID:CHEM201102326
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201102326