Reference Correlation for the Viscosity of Carbon Dioxide

• Published in: Journal of physical and chemical reference data Vol. 46; no. 1; pp. 13107 - 13134
• Main Authors: Laesecke, Arno, Muzny, Chris D.
• Format: Journal Article
• Language: English
• Published: United States American Institute of Physics (AIP) 01.03.2017
• Subjects: INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; carbon dioxide; Rainwater-Friend theory; viscosity; data analysis; thermophysical properties; critical enhancement; thermodynamic scaling; Carbon dioxide
• ISSN: 0047-2689; 1529-7845
• DOI: 10.1063/1.4977429

A comprehensive database of experimental and computed data for the viscosity of carbon dioxide (CO2) was compiled and a new reference correlation was developed. Literature results based on an ab initio potential energy surface were the foundation of the correlation of the viscosity in the limit of zero density in the temperature range from 100 to 2000 K. Guided symbolic regression was employed to obtain a new functional form that extrapolates correctly to 0 and to 10 000 K. Coordinated measurements at low density made it possible to implement the temperature dependence of the Rainwater-Friend theory in the linear-in-density viscosity term. The residual viscosity could be formulated with a scaling term ρ γ /T, the significance of which was confirmed by symbolic regression. The final viscosity correlation covers temperatures from 100 to 2000 K for gaseous CO2 and from 220 to 700 K with pressures along the melting line up to 8000 MPa for compressed and supercritical liquid states. The data representation is more accurate than with the previous correlations, and the covered pressure and temperature range is significantly extended. The critical enhancement of the viscosity of CO2 is included in the new correlation.