Recent advances in enantioselective ring-opening polymerization and copolymerization
Precisely controlling macromolecular stereochemistry and sequences is a powerful strategy for manipulating polymer properties. Controlled synthetic routes to prepare degradable polyester, polycarbonate, and polyether are of recent interest due to the need for sustainable materials as alternatives to...
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Published in | Communications chemistry Vol. 6; no. 1; p. 202 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
London
Nature Publishing Group UK
29.09.2023
Nature Publishing Group Nature Portfolio |
Subjects | |
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Abstract | Precisely controlling macromolecular stereochemistry and sequences is a powerful strategy for manipulating polymer properties. Controlled synthetic routes to prepare degradable polyester, polycarbonate, and polyether are of recent interest due to the need for sustainable materials as alternatives to petrochemical-based polyolefins. Enantioselective ring-opening polymerization and ring-opening copolymerization of racemic monomers offer access to stereoregular polymers, specifically enantiopure polymers that form stereocomplexes with improved physicochemical and mechanical properties. Here, we highlight the state-of-the-art of this polymerization chemistry that can produce microstructure-defined polymers. In particular, the structures and performances of various homogeneous enantioselective catalysts are presented. Trends and future challenges of such chemistry are discussed.
Stereoregular polymers exhibit improved thermal and mechanical properties, making the development of enantioselective polymerization catalysts of significant importance. Here, the authors summarize catalyst design strategies and synthetic routes for enantioselective polymerizations of degradable or recyclable polymers from racemic monomers. |
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AbstractList | Precisely controlling macromolecular stereochemistry and sequences is a powerful strategy for manipulating polymer properties. Controlled synthetic routes to prepare degradable polyester, polycarbonate, and polyether are of recent interest due to the need for sustainable materials as alternatives to petrochemical-based polyolefins. Enantioselective ring-opening polymerization and ring-opening copolymerization of racemic monomers offer access to stereoregular polymers, specifically enantiopure polymers that form stereocomplexes with improved physicochemical and mechanical properties. Here, we highlight the state-of-the-art of this polymerization chemistry that can produce microstructure-defined polymers. In particular, the structures and performances of various homogeneous enantioselective catalysts are presented. Trends and future challenges of such chemistry are discussed. Precisely controlling macromolecular stereochemistry and sequences is a powerful strategy for manipulating polymer properties. Controlled synthetic routes to prepare degradable polyester, polycarbonate, and polyether are of recent interest due to the need for sustainable materials as alternatives to petrochemical-based polyolefins. Enantioselective ring-opening polymerization and ring-opening copolymerization of racemic monomers offer access to stereoregular polymers, specifically enantiopure polymers that form stereocomplexes with improved physicochemical and mechanical properties. Here, we highlight the state-of-the-art of this polymerization chemistry that can produce microstructure-defined polymers. In particular, the structures and performances of various homogeneous enantioselective catalysts are presented. Trends and future challenges of such chemistry are discussed. Stereoregular polymers exhibit improved thermal and mechanical properties, making the development of enantioselective polymerization catalysts of significant importance. Here, the authors summarize catalyst design strategies and synthetic routes for enantioselective polymerizations of degradable or recyclable polymers from racemic monomers. Abstract Precisely controlling macromolecular stereochemistry and sequences is a powerful strategy for manipulating polymer properties. Controlled synthetic routes to prepare degradable polyester, polycarbonate, and polyether are of recent interest due to the need for sustainable materials as alternatives to petrochemical-based polyolefins. Enantioselective ring-opening polymerization and ring-opening copolymerization of racemic monomers offer access to stereoregular polymers, specifically enantiopure polymers that form stereocomplexes with improved physicochemical and mechanical properties. Here, we highlight the state-of-the-art of this polymerization chemistry that can produce microstructure-defined polymers. In particular, the structures and performances of various homogeneous enantioselective catalysts are presented. Trends and future challenges of such chemistry are discussed. Abstract Precisely controlling macromolecular stereochemistry and sequences is a powerful strategy for manipulating polymer properties. Controlled synthetic routes to prepare degradable polyester, polycarbonate, and polyether are of recent interest due to the need for sustainable materials as alternatives to petrochemical-based polyolefins. Enantioselective ring-opening polymerization and ring-opening copolymerization of racemic monomers offer access to stereoregular polymers, specifically enantiopure polymers that form stereocomplexes with improved physicochemical and mechanical properties. Here, we highlight the state-of-the-art of this polymerization chemistry that can produce microstructure-defined polymers. In particular, the structures and performances of various homogeneous enantioselective catalysts are presented. Trends and future challenges of such chemistry are discussed. Precisely controlling macromolecular stereochemistry and sequences is a powerful strategy for manipulating polymer properties. Controlled synthetic routes to prepare degradable polyester, polycarbonate, and polyether are of recent interest due to the need for sustainable materials as alternatives to petrochemical-based polyolefins. Enantioselective ring-opening polymerization and ring-opening copolymerization of racemic monomers offer access to stereoregular polymers, specifically enantiopure polymers that form stereocomplexes with improved physicochemical and mechanical properties. Here, we highlight the state-of-the-art of this polymerization chemistry that can produce microstructure-defined polymers. In particular, the structures and performances of various homogeneous enantioselective catalysts are presented. Trends and future challenges of such chemistry are discussed.Stereoregular polymers exhibit improved thermal and mechanical properties, making the development of enantioselective polymerization catalysts of significant importance. Here, the authors summarize catalyst design strategies and synthetic routes for enantioselective polymerizations of degradable or recyclable polymers from racemic monomers. |
ArticleNumber | 202 |
Author | Tong, Rong Xie, Xiaoyu Jang, Eungyo Huo, Ziyu |
Author_xml | – sequence: 1 givenname: Xiaoyu surname: Xie fullname: Xie, Xiaoyu organization: Department of Chemical Engineering, Virginia Polytechnic Institute and State University – sequence: 2 givenname: Ziyu surname: Huo fullname: Huo, Ziyu organization: Department of Chemical Engineering, Virginia Polytechnic Institute and State University – sequence: 3 givenname: Eungyo surname: Jang fullname: Jang, Eungyo organization: Department of Chemical Engineering, Virginia Polytechnic Institute and State University – sequence: 4 givenname: Rong orcidid: 0000-0002-2034-9272 surname: Tong fullname: Tong, Rong email: rtong@vt.edu organization: Department of Chemical Engineering, Virginia Polytechnic Institute and State University |
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CitedBy_id | crossref_primary_10_1021_acscatal_3c04955 crossref_primary_10_1021_acs_macromol_4c00563 crossref_primary_10_1039_D4CC02501F crossref_primary_10_1021_jacs_3c14091 crossref_primary_10_1038_s42004_024_01134_1 crossref_primary_10_3390_ijms25031647 crossref_primary_10_1021_acscatal_3c05103 crossref_primary_10_1002_ange_202405382 crossref_primary_10_1002_anie_202405382 crossref_primary_10_1021_acs_macromol_3c02477 |
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Snippet | Precisely controlling macromolecular stereochemistry and sequences is a powerful strategy for manipulating polymer properties. Controlled synthetic routes to... Abstract Precisely controlling macromolecular stereochemistry and sequences is a powerful strategy for manipulating polymer properties. Controlled synthetic... Abstract Precisely controlling macromolecular stereochemistry and sequences is a powerful strategy for manipulating polymer properties. Controlled synthetic... |
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Title | Recent advances in enantioselective ring-opening polymerization and copolymerization |
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