Linking the effect of localised pitting corrosion with mechanical integrity of a rare earth magnesium alloy for implant use

• Published in: Bioactive materials Vol. 21; pp. 32 - 43
• Main Authors: van Gaalen, Kerstin, Quinn, Conall, Benn, Felix, McHugh, Peter E., Kopp, Alexander, Vaughan, Ted J.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.03.2023; KeAi Publishing; KeAi Communications Co., Ltd
• Subjects: Corrosion modelling; FEM; Localised corrosion; Magnesium; Phenomenology; Phenomenology; Localised corrosion; Magnesium; Corrosion modelling; FEM
• ISSN: 2452-199X; 2452-199X
• DOI: 10.1016/j.bioactmat.2022.08.004

This study presents a computational framework that investigates the effect of localised surface-based corrosion on the mechanical performance of a magnesium-based alloy. A finite element-based phenomenological corrosion model was used to generate a wide range of corrosion profiles, with subsequent uniaxial tensile test simulations to predict the mechanical response to failure. The python-based detection framework PitScan provides detailed quantification of the spatial phenomenological features of corrosion, including a full geometric tracking of corroding surface. Through this approach, this study is the first to quantitatively demonstrate that a surface-based non-uniform corrosion model can capture both the geometrical and mechanical features of a magnesium alloy undergoing corrosion by comparing to experimental data. Using this verified corrosion modelling approach, a wide range of corrosion scenarios was evaluated and enabled quantitative relationships to be established between the mechanical integrity and key phenomenological corrosion features. In particular, we demonstrated that the minimal cross-sectional area parameter was the strongest predictor of the remaining mechanical strength (R2 = 0.98), with this relationship being independent of the severity or spatial features of localised surface corrosion. Interestingly, our analysis demonstrated that parameters described in ASTM G46-94 showed weaker correlations to the mechanical integrity of corroding specimens, compared to parameters determined by Pitscan. This study establishes new mechanistic insight into the performance of the magnesium-based materials undergoing corrosion. [Display omitted] •Corrosion profile (uniform/localised) generation with phenomenological degradation model.•Automated phenomenological tracking of corrosion features by PitScan.•Linking mechanical key parameters and geometrical corrosion features including in-vitro data.•Identification of profile independent corrosion features and model fitting.